Nernst plots and formal potentials in a nonpolar solvent consisting of aluminum bromide (Al2Br6) and potassium bromide in ethylbenzene

1984 ◽  
Vol 88 (8) ◽  
pp. 1609-1615 ◽  
Author(s):  
M. Elam ◽  
I. Bahatt ◽  
E. Peled ◽  
E. Gileadi
Author(s):  
G. E. Bacon ◽  
D. H. Titterton ◽  
C. R. Walker

AbstractNeutron-diffraction data have been collected from a KBr single crystal. 380 reflections were measured, reducing to 23 when averaged over equivalents. Data were corrected for extinction and thermal diffuse scattering and refinement yielded a neutron coherent scattering amplitude


2019 ◽  
Author(s):  
Caroline C. Warner ◽  
andrea thooft ◽  
Bryan J. Lampkin ◽  
selin demirci ◽  
Brett VanVeller

<p>A strategy to control the efficiency of a photocleavage reaction based on changing the nature of the excited state is presented. A novel class of photoactive compounds has been synthesized by combining the classical o-nitrobenzyl scaffold with an environmentally sensitive dye, 4-amino-nitrobenzothiazole. Irradiation in a polar solvent lead to an excited state that is inoperative for photochemistry whereas excitation in a nonpolar solvent lead to an excited state that is photochemically active. A photochemical degradation appears to be the preferred process in contrast to the intended photocleavage process.</p>


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