Light-scattering studies of phase separation in isobutyric acid + water mixtures. 2. Test of scaling

1981 ◽  
Vol 85 (14) ◽  
pp. 1972-1976 ◽  
Author(s):  
Charles M. Knobler ◽  
Ning-Chih Wong
Keyword(s):  
Phase Separation ◽  
Light Scattering ◽  
Isobutyric Acid ◽  
Acid Water

Excess partial molar enthalpies in the water-rich region of the isobutyric acid – water system

1991 ◽  
Vol 69 (7) ◽  
pp. 1065-1069 ◽  
Author(s):  
William W. Y. Siu ◽  
Terrance Y. H. Wong ◽  
Lisa C. F. Chao ◽  
Yoshikata Koga
Keyword(s):  
Phase Separation ◽  
Water System ◽  
Isobutyric Acid ◽  
Acid Water ◽  
Rich Region ◽  
Two Phase ◽  
Fourth Derivative ◽  
Mixing Schemes ◽  
Partial Molar Enthalpies ◽  
Structure Enhancement

The excess partial molar enthalpies of isobutyric acid (IBA), HmE(IBA), and those of H2O, HmE(H2O), were measured in aqueous solutions of IBA. The temperature dependence of HmE(IBA) at the infinite dilution suggested that the structure enhancement of the solvent H2O by IBA is weaker than those by tert-butanol (TBA) or 2-butoxyethanol (BE). The concentration dependence of HmE(IBA), and that of the enthalpic IBA–IBA interaction, N{∂HmE(IBA)/∂nB}, shows that there are two distinct mixing schemes bounded at about xB = 0.03, before reaching the two phase separation. Namely, the IBA–IBA interaction is repulsive below this boundary, while above this boundary it becomes attractive leading eventually to phase separation at a higher concentration. The transition between the two schemes is associated with a peak(negative) anomally in the fourth derivative of the free energy, N2 {∂2HmE(IBA)/∂nB2}.Key words: excess partial molar enthalpies, isobutyric acid – water, transition in mixing scheme.

Light Scattering and Pseudospinodal Curves: The Isobutyric-Acid-Water System in the Critical Region

1969 ◽  
Vol 185 (1) ◽  
pp. 219-226 ◽  
Author(s):  
B. Chu ◽  
F. J. Schoenes ◽  
Michael E. Fisher
Keyword(s):  
Light Scattering ◽  
Critical Region ◽  
Water System ◽  
Isobutyric Acid ◽  
Acid Water

A Time-Resolved Low-Angle Light Scattering Apparatus. Application to Phase Separation Problems in Polymer Systems

2001 ◽  
Vol 66 (6) ◽  
pp. 973-982 ◽  
Author(s):  
Čestmír Koňák ◽  
Jaroslav Holoubek ◽  
Petr Štěpánek
Keyword(s):  
Phase Separation ◽  
Light Scattering ◽  
Signal To Noise Ratio ◽  
Scattered Light ◽  
Ccd Camera ◽  
Time Resolved ◽  
Polymer Systems ◽  
Software Analysis ◽  
Phase Separation Kinetics ◽  
Small Angle Light Scattering

A time-resolved small-angle light scattering apparatus equipped with azimuthal integration by means of a conical lens or software analysis of scattering patterns detected with a CCD camera was developed. Averaging allows a significant reduction of the signal-to-noise ratio of scattered light and makes this technique suitable for investigation of phase separation kinetics. Examples of applications to time evolution of phase separation in concentrated statistical copolymer solutions and dissolution of phase-separated domains in polymer blends are given.

Phase Separation and Spatial Morphology in Sodium Silicate Glasses by AFM, Light Scattering and NMR

2013 ◽  
Vol 96 (8) ◽  
pp. 2454-2460 ◽  
Author(s):  
Abbas Hodroj ◽  
Patrick Simon ◽  
Pierre Florian ◽  
Marie-Hélène Chopinet ◽  
Yann Vaills
Keyword(s):  
Phase Separation ◽  
Light Scattering ◽  
Sodium Silicate ◽  
Silicate Glasses ◽  
Spatial Morphology
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