Electron-transfer kinetics from cyclic voltammetry. Quantitative description of electrochemical reversibility

1981 ◽  
Vol 85 (12) ◽  
pp. 1731-1741 ◽  
Author(s):  
R. J. Klingler ◽  
J. K. Kochi
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Quantitative Description ◽  
Electron Transfer Kinetics ◽  
Electrochemical Reversibility

Resolving electron transfer kinetics in porous electrodes via diffusion-less cyclic voltammetry

2021 ◽  
Author(s):  
Shida Yang ◽  
Yang Li ◽  
Qing Chen
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Reaction Rates ◽  
Porous Electrodes ◽  
Three Dimensions ◽  
Electrochemical Cells ◽  
Electron Transfer Kinetics ◽  
Electrolyte Interface

Porous electrodes are cornerstones in advanced electrochemical cells. They extend the electrode/electrolyte interface to three dimensions to boost reaction rates with high specific areas. The rate, however, depends on not...

scholarly journals Carbon Nanotube Yarn Microelectrodes Promote High Temporal Measurements of Serotonin Using Fast Scan Cyclic Voltammetry

Sensors ◽  
2020 ◽  
Vol 20 (4) ◽  
pp. 1173 ◽  
Author(s):  
Alexander Mendoza ◽  
Thomas Asrat ◽  
Favian Liu ◽  
Pauline Wonnenberg ◽  
Alexander G. Zestos
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Carbon Nanotube ◽  
Electrode Materials ◽  
Cyclic Voltammograms ◽  
Electron Transfer Kinetics ◽  
Fast Scan Cyclic Voltammetry ◽  
Peak Separation ◽  
Aspect Ratios ◽  
Carbon Fiber Microelectrodes

Carbon fiber-microelectrodes (CFMEs) have been the standard for neurotransmitter detection for over forty years. However, in recent years, there have been many advances of utilizing alternative nanomaterials for neurotransmitter detection with fast scan cyclic voltammetry (FSCV). Recently, carbon nanotube (CNT) yarns have been developed as the working electrode materials for neurotransmitter sensing capabilities with fast scan cyclic voltammetry. Carbon nanotubes are ideal for neurotransmitter detection because they have higher aspect ratios enabling monoamine adsorption and lower limits of detection, faster electron transfer kinetics, and a resistance to surface fouling. Several methods to modify CFMEs with CNTs have resulted in increases in sensitivity, but have also increased noise and led to irreproducible results. In this study, we utilize commercially available CNT-yarns to make microelectrodes as enhanced neurotransmitter sensors for neurotransmitters such as serotonin. CNT-yarn microelectrodes have significantly higher sensitivities (peak oxidative currents of the cyclic voltammograms) than CFMEs and faster electron transfer kinetics as measured by peak separation (ΔEP) values. Moreover, both serotonin and dopamine are adsorption controlled to the surface of the electrode as measured by scan rate and concentration experiments. CNT yarn microelectrodes also resisted surface fouling of serotonin onto the surface of the electrode over thirty minutes and had a wave application frequency independent response to sensitivity at the surface of the electrode.

Studies on electrooxidation of lignin and lignin model compounds. Part 1: Direct electrooxidation of non-phenolic lignin model compounds

Holzforschung ◽  
2012 ◽  
Vol 66 (3) ◽  
Author(s):  
Takumi Shiraishi ◽  
Toshiyuki Takano ◽  
Hiroshi Kamitakahara ◽  
Fumiaki Nakatsubo
Keyword(s):  
Electron Transfer ◽  
Cyclic Voltammetry ◽  
Carbonyl Compounds ◽  
Model Compounds ◽  
Lignin Model Compounds ◽  
Bulk Electrolysis ◽  
Lignin Model ◽  
Dimeric Compound ◽  
High Yields ◽  
Short Time

Abstract The direct anodic oxidation of non-phenolic lignin model compounds was investigated to understand their basic behaviors. The results of cyclic voltammetry (CV) studies of monomeric model, such as 1-(4-ethoxy-3-methoxyphenyl)ethanol, are interpreted as the oxidation for Cα-carbonylation did not proceed in the reaction without a catalyst, but a base promotes this reaction. Indeed, the bulk electrolyses of the monomeric lignin model compounds with 2,6-lutidine afforded the corresponding Cα-carbonyl compounds in high yields (60–80%). It is suggested that deprotonation at Cα-H in the ECEC mechanism (E=electron transfer and C=chemical step) is important for Cα-carbonylation. In the uncatalyzed bulk electrolysis of a β-O-4 model dimeric compound, 4-ethoxy-3-methoxyphenylglycerol-β-guaiacyl ether, the corresponding Cα-carbonyl compound was not detected but as a result of Cα-Cβcleavage 4-O-ethylvanillin was found in 40% yield. In the electrolysis reaction in the presence of 2,6-lutidine (as a sterically hindered light base), the reaction stopped for a short time unexpectedly. These results indicate the different electrochemical behavior of simple monomeric model compounds and dimeric β-O-4 models. The conclusion is that direct electrooxidation is unsuitable for Cα-carbonylation of lignin.

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