Partial Vapor Pressure and Entropy of Solution of Iodine

1959 ◽  
Vol 63 (7) ◽  
pp. 1174-1174 ◽  
Author(s):  
John Walkley ◽  
Joel H. Hildebr
Keyword(s):  
Vapor Pressure ◽  
Partial Vapor Pressure

Solvolysis of isopropyl bromide in ethanol–water mixtures. Dissection into initial state and transition state contributions

1976 ◽  
Vol 54 (24) ◽  
pp. 3944-3948 ◽  
Author(s):  
Wiendelt Drenth ◽  
Michael Cocivera
Keyword(s):  
Vapor Pressure ◽  
Transition State ◽  
Thermodynamic Parameters ◽  
Activation Parameters ◽  
Solvent Composition ◽  
Initial State ◽  
Partial Vapor Pressure ◽  
State Variation

Rates were determined for the solvolysis of isopropyl bromide in ethanol–water mixtures (20 to 80% by volume of ethanol) at 50 and 75 °C and the corresponding activation parameters calculated. From the partial vapor pressure of isopropyl bromide over the various solutions at 50 and 75 °C, the variations in its initial state thermodynamic parameters were calculated. Thus, the variation in the activation parameters with solvent composition could be analyzed in terms of initial and transition state contributions. The initial state variation dominates according to a unimolecular as well as to a bimolecular treatment of data.

scholarly journals Volatilization Behavior of Manganese from Molten Steel with Different Alloying Methods in Vacuum

Metals ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1348
Author(s):  
Jianhua Chu ◽  
Yanping Bao
Keyword(s):  
Vapor Pressure ◽  
Carbon Content ◽  
Thermodynamic Analysis ◽  
Molten Steel ◽  
Manganese Steel ◽  
Volatile Fraction ◽  
High Carbon ◽  
Partial Vapor Pressure ◽  
High Carbon Ferromanganese ◽  
Volatilization Behavior

The volatilization loss of manganese during the vacuum smelting process is one of the key factors that determines the manufacturing cost and quality of manganese steel. In this study, the laboratory experiments and thermodynamic calculations were performed to investigate volatilization behavior of manganese from molten steels with different alloying methods in vacuum process. Based on the thermodynamic analysis, with the increase of manganese content, the partial vapor pressure of the manganese component increased, resulting in manganese being easily volatilized from molten steel. The carbon content in the steel shows an evident influence on partial vapor pressure of manganese component, and a higher carbon content in steel leads to a lower partial vapor pressure of manganese, but it not influenced by the silicon content. Compared with the alloying method of high carbon ferromanganese, the volatilization loss of manganese in the alloying method of silicon manganese presents faster decay, agreeing well with the thermodynamic analysis. Besides, the volatile fraction generated in the alloying method of high-carbon ferromanganese is composed of a large amount of MnO nanorods with a lateral length approximately 500 nm and a small number of Mn3O4/Mn nanoparticles with a diameter less than 500 nm. Additionally, the volatile fraction generated in the alloying method of silicon manganese shows Mn3O4 nanoparticles as the main phase. It can be inferred that the existence of the manganese oxide phase is attributed to the high chemical activity of nanoscale particles within air.

scholarly journals Dependency of continuum model parameters on the spatially correlated pore structure studied by pore-network drying simulations

2018 ◽  
Author(s):  
Abdolreza Kharaghani ◽  
Xiang Lu ◽  
Evangelos Tsotsas
Keyword(s):  
Vapor Pressure ◽  
Pore Structure ◽  
Moisture Transport ◽  
Transport Coefficient ◽  
Continuum Model ◽  
Pore Network ◽  
Partial Vapor Pressure ◽  
Spatially Correlated ◽  
Pore Structures ◽  
Network Simulations

Pore-network simulations are carried out for monomodal and bimodal pore structures with spatially correlated pore-size distributions. The internal and surface relationships between the partial vapor pressure and saturation as well as the moisture transport coefficient for these model porous structures are identified from the post-processing of the corresponding pore-network model solutions. The simulation results show that the deviation of the partial vapor pressure from the saturation vapor pressure in the presence of liquid – which is referred to as non-local equilibrium effect – in the bimodal pore structures is less pronounced than in the monomodal pore structures. For the monomodal pore structures the moisture transport coefficient profile is not unique over the entire drying process, whereas this profile depends marginally on the drying history of the bimodal pore structures. Finally the ability of the continuum model to predict the results of the pore-network simulations for multiple realizations of the pore space is assessed. Keywords: Scale transition, Moisture transport coefficient, Pore structure, Discrete model, Continuum model  

Partial vapor pressure of CO2 and H2S over aqueous methyldiethanolamine solutions

2000 ◽  
Vol 172 (2) ◽  
pp. 261-277 ◽  
Author(s):  
B. Lemoine ◽  
Yi-Gui Li ◽  
R. Cadours ◽  
C. Bouallou ◽  
D. Richon
Keyword(s):  
Vapor Pressure ◽  
Partial Vapor Pressure

Benzylamine Tartrate as an Organic Glass Substrate for Carbon Films by Evaporation

1970 ◽  
Vol 28 ◽  
pp. 484-485
Author(s):  
A. C. Faberge
Keyword(s):  
Vapor Pressure ◽  
Viscous Liquid ◽  
Glass Substrate ◽  
Room Temperature ◽  
Carbon Film ◽  
Carbon Films ◽  
Organic Glass ◽  
Spectroscopic Examination ◽  
Polymeric Substrates

Benzylamine tartrate (m.p. 63°C) seems to be a better and more convenient substrate for making carbon films than any of those previously proposed. Using it in the manner described, it is easy consistently to make batches of specimen grids as open as 200 mesh with no broken squares, and without individual handling of the grids. Benzylamine tartrate (hereafter called B.T.) is a viscous liquid when molten, which sets to a glass. Unlike polymeric substrates it does not swell before dissolving; such swelling of the substrate seems to be a principal cause of breakage of carbon film. Mass spectroscopic examination indicates a vapor pressure less than 10−9 Torr at room temperature.

Hydration Chamber for Jeolco 200 Kv Microscope

1970 ◽  
Vol 28 ◽  
pp. 542-543
Author(s):  
V. R. Matricardi ◽  
G. G. Hausner ◽  
D. F. Parsons
Keyword(s):  
Electron Microscope ◽  
Water Vapor ◽  
Vapor Pressure ◽  
Pressure Gradient ◽  
Room Temperature ◽  
List Type ◽  
Type Number ◽  
Equilibrium Vapor Pressure

In order to observe room temperature hydrated specimens in an electron microscope, the following conditions should be satisfied: The specimen should be surrounded by water vapor as close as possible to the equilibrium vapor pressure corresponding to the temperature of the specimen.The specimen grid should be inserted, focused and photo graphed in the shortest possible time in order to minimize dehydration.The full area of the specimen grid should be visible in order to minimize the number of changes of specimen required.There should be no pressure gradient across the grid so that specimens can be straddled across holes.Leakage of water vapor to the column should be minimized.

Sign in / Sign up

Export Citation Format

Share Document