Miscibility Relations of Liquid Hydrogen Cyanide

1959 ◽  
Vol 63 (5) ◽  
pp. 753-755 ◽  
Author(s):  
Alfred W. Francis
Keyword(s):  
Hydrogen Cyanide ◽  
Liquid Hydrogen

[UCl4(HCN)4] – a hydrogen cyanide complex of uranium tetrachloride

2018 ◽  
Vol 54 (10) ◽  
pp. 1241-1244 ◽  
Author(s):  
S. S. Rudel ◽  
C. Pietzonka ◽  
M. Hoelzel ◽  
F. Kraus
Keyword(s):  
Hydrogen Cyanide ◽  
Liquid Hydrogen ◽  
Cyanide Complex ◽  
Microcrystalline Powder ◽  
Uranium Tetrachloride

The reaction of uranium tetrachloride with anhydrous liquid hydrogen cyanide yields a turquoise microcrystalline powder of tetrachloridotetraformonitrileuranium(iv), [UCl4(HCN)4].

Hydrogen Cyanide Polymers from the Impact of Comet P/Shoemaker-Levy 9 on Jupiter

1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman
Keyword(s):  
Amino Acids ◽  
Solar System ◽  
Hydrogen Cyanide ◽  
Nitrogen Heterocycles ◽  
Laboratory Studies ◽  
Heterogeneous Solids ◽  
The Many ◽  
Comet Halley ◽  
The Impact ◽  
By Products

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.

Rotational spectrum and properties of a complex of hydrogen cyanide and chlorine monofluoride

1996 ◽  
Vol 88 (3) ◽  
pp. 673-682 ◽  
Author(s):  
K. HINDS ◽  
A.C. LEGON ◽  
J.H. HOLLOWAY
Keyword(s):  
Hydrogen Cyanide ◽  
Rotational Spectrum

Influence of Ultrasound on the Formation of High-energy Particle Tracks in a Liquid-hydrogen Bubble Chamber

1969 ◽  
Vol 99 (9) ◽  
pp. 149-151
Author(s):  
V.A. Akulichev ◽  
L.R. Gavrilov ◽  
V.G. Grebinnik ◽  
V.A. Zhukov ◽  
G. Libman ◽  
...  
Keyword(s):  
Bubble Chamber ◽  
High Energy ◽  
Liquid Hydrogen ◽  
High Energy Particle ◽  
Hydrogen Bubble ◽  
Hydrogen Bubble Chamber ◽  
Energy Particle ◽  
Particle Tracks
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