Infrared Spectrum and Barrier to Internal Rotation in Ethyl Fluoride

1958 ◽  
Vol 62 (7) ◽  
pp. 873-874 ◽  
Author(s):  
Edward Catalano ◽  
Kenneth S. Pitzer
Keyword(s):  
Infrared Spectrum ◽  
Internal Rotation ◽  
Ethyl Fluoride

ChemInform Abstract: FAR INFRARED SPECTRUM OF THE INTERNAL ROTATION IN METHYLAMINE

1982 ◽  
Vol 13 (30) ◽  
Author(s):  
C. BELORGEOT ◽  
V. STERN ◽  
N. GOFF ◽  
J. KACHMARSKY ◽  
K. D. MOELLER
Keyword(s):  
Infrared Spectrum ◽  
Internal Rotation ◽  
Far Infrared

Far-infrared spectrum of the internal rotation in methylamine

1982 ◽  
Vol 92 (1) ◽  
pp. 91-100 ◽  
Author(s):  
C. Belorgeot ◽  
V. Stern ◽  
N. Goff ◽  
J. Kachmarsky ◽  
K.D. Möller
Keyword(s):  
Infrared Spectrum ◽  
Internal Rotation ◽  
Far Infrared

The Infrared and Raman Spectra of Trifluoronitrosomethane

1974 ◽  
Vol 52 (18) ◽  
pp. 3149-3157 ◽  
Author(s):  
Herbert F. Shurvell ◽  
Shiv C. Dass ◽  
Robert D. Gordon
Keyword(s):  
Raman Spectrum ◽  
Infrared Spectrum ◽  
Potential Energy ◽  
Internal Rotation ◽  
Condensed Phase ◽  
Infrared And Raman Spectra ◽  
Vibrational Assignment ◽  
Normal Coordinate ◽  
Energy Distributions ◽  
Torsional Mode

The infrared spectrum of gaseous CF3NO has been studied in the region 4000–35 cm−1. The infrared spectrum of the condensed phase has also been recorded and a complete vibrational assignment is proposed. Attempts to record the Raman spectrum have been hampered by photolysis. A frequency of 50 cm−1 for the CF3 torsional mode has been estimated from combination and hot bands. This corresponds to a barrier to internal rotation of approximately 425 cal/mol (150 cm−1). A normal coordinate analysis has been carried out and potential energy distributions, and valence and symmetry force constants are reported.

Infrared spectrum, ab initio calculations, barriers to internal rotation and structural parameters for methyl nitrite

1990 ◽  
Vol 94 (10) ◽  
pp. 4029-4039 ◽  
Author(s):  
B. J. Van der Veken ◽  
R. Maas ◽  
G. A. Guirgis ◽  
H. D. Stidham ◽  
T. G. Sheehan ◽  
...  
Keyword(s):  
Infrared Spectrum ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Internal Rotation ◽  
Structural Parameters ◽  
Methyl Nitrite ◽  
Barriers To Internal Rotation
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