Correction: The Transference Numbers of Iodic Acid and the LImiting Mobility of the Iodate Ion in Aqueous Solutions at 25 Degrees

1956 ◽  
Vol 60 (12) ◽  
pp. 1673-1673 ◽  
Author(s):  
M. Spiro
1951 ◽  
Vol 73 (12) ◽  
pp. 5650-5652 ◽  
Author(s):  
E. P. Purser ◽  
R. H. Stokes

1845 ◽  
Vol 1 ◽  
pp. 326-328
Author(s):  
Connell

Since his last communication to the Society, the author has made a variety of experiments, with the view of farther testing the truth of the proposed law which limits the direct action of the voltaic current to the solvent, in solutions of primary elementary combinations in the more important solvents. All his researches have farther confirmed this law in regard to aqueous solutions. Amongst those which he has examined is an aqueous solution of iodic acid as a type of oxyacids; and he found that by connecting such a solution mixed with starch, with a solution of starch in water, by means of asbestus, no iodine was indicated when the starch solution was negative, but was immediately manifested when the iodic solution was negative from the reducing action of hydrogen. In the whole circumstances, he has no hesitation in concluding, “that when aqueous solutions of primary combinations of elementary bodies are submitted to voltaic agency, the dissolved substance is not directly decomposed by the current, but only the solvent.”


2010 ◽  
Vol 7 (1) ◽  
pp. 593-600
Author(s):  
Baghdad Science Journal

Transference numbers of the aqueous zinc chloride and zinc sulphate solutions have been measured for the concentrations 0.03, 0.05, 0.07, 0.09 and 0.1 mol.dm-3at 298.15K, by using the modified Hittorf method. The dependence of transference number on concentration of each electrolyte was also investigated in an attempt to explain the value of the limiting transference number. The Longsworth method has been used for the extrapolation of zinc transference number in aqueous solutions, using the values of the limiting transference numbers of the appropriate values of the limiting equivalent conductance, it was possible to determine the corresponding values of the limiting ion conductance for the cations and anions of the electrolytes. The density and specific conductivity of all solutions have been measured at 298.15K.


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