The Concentration Dependence of the Diffusion Coefficient of Raffinose in Dilute Aqueous Solution at 25°

1956 ◽  
Vol 60 (10) ◽  
pp. 1464-1465 ◽  
Author(s):  
Peter J. Dunlop
1954 ◽  
Vol 76 (16) ◽  
pp. 4219-4220 ◽  
Author(s):  
Herbert S. Harned ◽  
Milton Blander ◽  
Clarence L. Hildreth

1978 ◽  
Vol 56 (20) ◽  
pp. 2620-2623 ◽  
Author(s):  
Poyilath Varieth Balakrishnan

The relative volatilities of cyclohexylamine and morpholine in dilute aqueous solution have been measured in the temperature range 150 to 300 °C at the corresponding equilibrium vapour pressure of the solution. Cyclohexylamine strongly prefers the steam phase while morpholine has a relatively volatility close to that of water. In both cases an azeotrope of the amine and water, with a vapour pressure higher than that of either component, must exist; however, with morpholine and water azeotrope formation only occurs above 175 °C. The concentration dependence of the distribution between the steam and solution phases of both amines is explained in terms of their partial ionization in solution.


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