The Solubility and Activity Coefficient of Silver Acetate in Mixed Solvents.

1936 ◽  
Vol 40 (5) ◽  
pp. 649-659 ◽  
Author(s):  
F. H. MacDougall ◽  
Charles Edward Bartsch
Keyword(s):  
Activity Coefficient ◽  
Mixed Solvents ◽  
Silver Acetate

Activity coefficient assumptions in the determination of the association constant of thallium(I) chloride. III. Effects of other association reactions

1967 ◽  
Vol 20 (12) ◽  
pp. 2633 ◽  
Author(s):  
KH Khoo ◽  
MH Panckhurst
Keyword(s):  
Activity Coefficient ◽  
Sodium Acetate ◽  
Association Constant ◽  
Specific Interaction ◽  
Mixed Solvents ◽  
Sodium Perchlorate ◽  
Barium Chloride ◽  
Interaction Coefficients ◽  
Free Ions

Measurements are reported of the solubility of thallium(I) chloride in aqueous solutions of sodium acetate and thallium(I) perchlorate and in solutions of sodium chloride, barium chloride, and sodium perchlorate in 16.7, 30, and 60 wt. % methanol-water mixtures. The measurements in water are used to test the merits of two types of ionic activity coefficient expression. It is shown that it is necessary to take account of specific interactions between free ions and that this also allows for small amounts of other association reactions in the same solution. The possibility of allowing for subsidiary association without using specific interaction coefficients is discussed, and it is concluded that this cannot be done in a completely satisfactory way. Measurements in mixed solvents are used to determine association parameters for the complex TlCl.

Solubility Prediction of Different Forms of Pharmaceuticals in Single and Mixed Solvents Using Symmetric Electrolyte Nonrandom Two-Liquid Segment Activity Coefficient Model

2019 ◽  
Vol 58 (10) ◽  
pp. 4267-4276 ◽  
Author(s):  
Getachew S. Molla ◽  
Michael Frederick Freitag ◽  
Stuart Michael Stocks ◽  
Kim Troensegaard Nielsen ◽  
Gürkan Sin
Keyword(s):  
Activity Coefficient ◽  
Mixed Solvents ◽  
Solubility Prediction ◽  
Activity Coefficient Model

The Equivalent Conductance of Electrolytes in Mixed Solvents

1958 ◽  
Vol 17 (5_6) ◽  
pp. 300-314 ◽  
Author(s):  
Rayburn Whorton ◽  
Edward S. Amis
Keyword(s):  
Mixed Solvents ◽  
Equivalent Conductance
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