The Fictive Volumes of Sodium Sulphate in Aqueous Solutions of Sulphuric Acid and of Iodine in an Aqueous Solution of Potassium Iodide

1931 ◽  
Vol 35 (3) ◽  
pp. 690-699 ◽  
Author(s):  
R. E. Gibson
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Sulphuric Acid ◽  
Potassium Iodide ◽  
Sodium Sulphate

Equilibrium between Sulphuric Acid and Sulphates in Aqueous Solution

1899 ◽  
Vol 22 ◽  
pp. 484-522
Author(s):  
Sydney A. Kay
Keyword(s):  
Aqueous Solution ◽  
Sulphuric Acid ◽  
Free Acid ◽  
Sodium Sulphate ◽  
Mass Action ◽  
Law Of Mass Action ◽  
Acid Sulphate ◽  
General Law ◽  
Influence Of Water ◽  
Mutual Action

In the year 1847, as one of the results of an investigation to determine the part played by the mass action of water in chemical reactions, H. Rose (Pogg. Ann., lxxxii. 545) showed that an acid sulphate in aqueous solution is progressively decomposed into free acid and neutral sulphate by increasing quantities of water. His observations were confirmed and extended by the thermo-chemical researches of Thomsen (Pogg. Ann. 1869, cxxxviii. 72), and Berthelot (Ann. Chim. Phys., 1873, xxix. 433), who indicated more exactly the course and extent of this decomposition, and from whose work it is known that in the solution of an acid sulphate there exist free sulphuric acid, neutral sulphate and acid sulphate. Finally Ostwald, in his first memoir on chemical affinity (Jour, prakt. Cliem. 1879, xix. 483), showed how to determine the magnitude of this decomposition, and was able to approximately measure the quantity of free acid in solutions of the acid sulphates at different dilutions. In a later paper (ibid., 1880, xxii. 305), Ostwald investigated the question of the influence of water on the action between sulphuric acid and a neutral sulphate. He measured the changes of volume which occurred when solutions of sulphuric acid and sodium sulphate were mixed in varying proportions, and at different dilutions, and obtained results in agreement with his previous work. He also pointed out, that if the mutual action between the acid and neutral sulphate obeyed the general law of mass action, it should follow that, for example, one molecule sodium sulphate plus three molecules sulphuric acid, give the same quantity of acid sulphate as one molecule sulphuric acid, and three molecules sodium sulphate, the volume of the mixture being the same in each case.

Chlorine Dioxide Gas from an Aqueous Solution: Reduction of Salmonella in Wounds on Tomato Fruit and Movement to Sinks in a Treatment Chamber

2009 ◽  
Vol 72 (5) ◽  
pp. 952-958 ◽  
Author(s):  
MICHAEL MAHOVIC ◽  
JERRY A. BARTZ ◽  
KEITH R. SCHNEIDER ◽  
JOEL D. TENNEY
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Potassium Iodide ◽  
Chlorine Dioxide ◽  
Initial Dose ◽  
Laboratory Experiments ◽  
Tomato Fruit ◽  
Chlorine Dioxide Gas ◽  
Viable Cells ◽  
Source To Sink

Chlorine dioxide (ClO2) off-gassed from an aqueous solution and reacted incrementally with potassium iodide solutions (sinks). After 30 min, 45% of the initial dose was detected as chlorite ion in the sink, whereas 35% of the initial dose was still in the source. Aqueous solutions of ClO2 can be used as a source of ClO2 gas in various laboratory experiments involving treatment of fruits or vegetables. Movement from source to sink is continuous, which precludes the development of large headspace concentrations and the need for a tight chamber seal. When the source solution has dissipated, the chamber can be opened safely as there is little free ClO2 remaining in the headspace. In tests with whole, wound-inoculated tomato fruit, at both green and pink stages of ripeness, the control of Salmonella enterica serotype Typhimurium in wounds varied with the weight of gas used. The number of viable cells of Typhimurium recovered was reduced by >5 log units when ≥0.5 mg of ClO2 was applied to three pieces of fruit during a 2-h treatment.

Effect of thermal history of aqueous solutions of KCl on the metastable zone width

1984 ◽  
Vol 49 (3) ◽  
pp. 559-569 ◽  
Author(s):  
Jaroslav Nývlt
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Thermal History ◽  
Equilibrium Solubility ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Preceding Experiment ◽  
History Of ◽  
Metastable Zone ◽  
The Given

The metastable zone width of an aqueous solution of KCI was measured as a function of the time and temperature of overheating above the equilibrium solubility temperature. It has been found that when the experiments follow close upon one another, the parameters of the preceding experiment affect the results of the experiment to follow.The results are interpreted in terms of hypotheses advanced in the literature to account for the effect of thermal history of solution. The plausibility and applicability of these hypotheses are assessed for the given cause of aqueous solution of a well soluble electrolyte.

scholarly journals I. Thermo-electric behaviour of aqueous solutions with mercurial electrodes

1879 ◽  
Vol 29 (196-199) ◽  
pp. 472-482 ◽  
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Internal Diameter ◽  
Thermo Electric ◽  
Thin Glass ◽  
Mercury Surface

In order to investigate this subject, I devised and constructed the following apparatus :—A and B are two thin glass basins, 81 millims. internal diameter (= 5,153 sq. millims. of mercury surface), and 6·0 centims. deep; each containing a layer of mercury about 1·0 centim. deep, covered by a layer, about 3 centims. deep, of the aqueous solution to be examined.

scholarly journals Meta-studtite stability in aqueous solutions. Impact of HCO3−, H2O2 and ionizing radiation on dissolution and speciation

2021 ◽  
Author(s):  
Junyi Li ◽  
Zoltán Szabó ◽  
Mats Jonsson
Keyword(s):  
Aqueous Solution ◽  
Ionizing Radiation ◽  
Aqueous Solutions ◽  
Carbonate Complexes ◽  
C Nmr

Four different uranyl-(peroxide)-carbonate complexes were identified during studtite and meta-studtite dissolution in aqueous solution containing 10 mM HCO3− by 13C NMR.

scholarly journals Visualization of microwave near-field distribution in sodium chloride and glucose aqueous solutions by a thermo-elastic optical indicator microscope

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zhirayr Baghdasaryan ◽  
Arsen Babajanyan ◽  
Levon Odabashyan ◽  
Jung-Ha Lee ◽  
Barry Friedman ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Field Distribution ◽  
Near Field ◽  
Absorption Properties ◽  
Novel Approach ◽  
Concentration Changes ◽  
Biological Liquids ◽  
Optical Indicator ◽  
Distribution Intensity

AbstractIn this study, a new optical method is presented to determine the concentrations of NaCl and glucose aqueous solutions by using a thermo-elastic optical indicator microscope. By measuring the microwave near-field distribution intensity, concentration changes of NaCl and glucose aqueous solutions were detected in the 0–100 mg/ml range, when exposed to microwave irradiation at 12 GHz frequency. Microwave near-field distribution intensity decreased as the NaCl or glucose concentration increased due to the changes of the absorption properties of aqueous solution. This method provides a novel approach for monitoring NaCl and glucose in biological liquids by using a CCD sensor capable of visualizing NaCl and glucose concentrations without scanning.

Fabrication of monodisperse polypyrrole/SBA-15 composite for the selective removal of Cr(Ⅵ) from aqueous solutions

2021 ◽  
Author(s):  
Liang Wang ◽  
Peng Gao ◽  
Mengxin Liu ◽  
Ziqing Huang ◽  
Shixia Lan ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Adsorption Process ◽  
In Situ Polymerization ◽  
Selective Removal ◽  
Factors Affecting

Monodisperse polypyrrole/SBA-15 composite (PPy/SBA-15) was fabricated by in-situ polymerization and used for Cr(Ⅵ) adsorption from aqueous solution. PPy/SBA-15 was characterized by numerous approaches. Factors affecting the Cr(Ⅵ) adsorption process included...

The synthesis of Cyclododecane-r-1,c-5,c-9-triamine and r-1,c-5,c-9-Tris(2,3-dimethoxybenzamido)cyclododecane

1975 ◽  
Vol 28 (3) ◽  
pp. 673 ◽  
Author(s):  
DJ Collins ◽  
C Lewis ◽  
JM Swan
Keyword(s):  
Aqueous Solution ◽  
Acid Hydrolysis ◽  
Sulphuric Acid ◽  
Sodium Carbonate ◽  
Sodium Azide ◽  
Room Temperature ◽  
Dimethyl Formamide ◽  
Lithium Aluminium Hydride ◽  
Lithium Aluminium ◽  
Hydrolysis Of

Treatment of cyclododecane-r-1,c-5,c-9-triyl tris(p-toluenesulphonate) with sodium azide in dimethyl-formamide at 100� for 6 h gave the corresponding cis,cis-triazide which upon hydrogenation or reduction with lithium aluminium hydride gave cyclododecane-r-1,c-5,c-9-triamine, isolated as the tris-salicylidene derivative. Acid hydrolysis of this, removal of the salicylaldehyde, and treatment of the aqueous solution with sodium carbonate and 2,3-dimethoxybenzoyl chloride gave r-1,c-5,c- 9-tris(2,3-dimethoxybenzamido)cyclododecane. ��� Treatment of (E,E,E)-cyclododeca-1,5,9-triene with an excess of acetonitrile and sulphuric acid at room temperature for three days gave 18% of (E,E)-1-acetamidocyclododeca-4,8-diene; no di- or tri-amides were isolated.

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