Radiation chemical yield of OH- as determined by conductometric pulse radiolysis

1971 ◽  
Vol 75 (11) ◽  
pp. 1759-1760 ◽  
Author(s):  
A. Henglein ◽  
J. Rabani ◽  
M. Graetzel ◽  
S. A. Chaudhri ◽  
G. Beck
Keyword(s):  
Pulse Radiolysis ◽  
Chemical Yield ◽  
Radiation Chemical Yield ◽  
Radiation Chemical

scholarly journals Radiation chemical yield for loss of carbonate ester bonds in PADC films exposed to gamma ray

2009 ◽  
Vol 44 (2) ◽  
pp. 211-213 ◽  
Author(s):  
Yutaka Mori ◽  
Toshiji Ikeda ◽  
Tomoya Yamauchi ◽  
Atsushi Sakamoto ◽  
Hiraku Chikada ◽  
...  
Keyword(s):  
Gamma Ray ◽  
Chemical Yield ◽  
Radiation Chemical Yield ◽  
Radiation Chemical

scholarly journals Polyethylene Outgassing Study for MEMS Nuclear Radiation Sensor

Proceedings ◽  
2018 ◽  
Vol 2 (13) ◽  
pp. 718
Author(s):  
Dheraaj Kumar ◽  
Julien Philippe ◽  
Samuel Charlot ◽  
Sandrine Assié ◽  
Aurélie Lecestre ◽  
...  
Keyword(s):  
Chemical Yield ◽  
High Energy ◽  
Nuclear Radiation ◽  
Pollution Level ◽  
Radiation Chemical Yield ◽  
Radiation Chemical ◽  
High Temperature Process ◽  
Radiation Sensor ◽  
Sensor Fabrication ◽  
Energy Gamma

In this paper, the out-gassing from PolyEthylene (PE) film is studied under nuclear irradiation for the design and fabrication of passive MEMS dosimeters. The fabrication of sensor needs high temperature process that leads to specific constraints on the PE film. Radiation chemical yield of hydrogen production (GH2) from PE under gamma irradiation is verified by mass spectroscopy after temperature annealing in vacuum up to 400 °C. Prototypes are fabricated to validate the fabrication of the sensor and then irradiated with high energy gamma radiation (with dose of 20 kGy). Measurements of membrane deflections after irradiation validate the GH2 factor, showing low pollution level of PE during sensor fabrication.

Radiation-Chemical Yield of Graph Copolymers in Radiation Grafting

1975 ◽  
Vol 8 (3) ◽  
pp. 276-279 ◽  
Author(s):  
Yoshito Ikada ◽  
Fumitaka Horii ◽  
Yasuko Nishizaki ◽  
Tomoe Kawahara ◽  
Hiroshi Uehara
Keyword(s):  
Chemical Yield ◽  
Radiation Grafting ◽  
Radiation Chemical Yield ◽  
Radiation Chemical

Radiation-chemical yield of excited neodymium(III) in laser liquids POCl3-MCln-235UO2 2+-Nd3+ (M = Ti, Zr, Sn, or Sb)

2007 ◽  
Vol 41 (2) ◽  
pp. 71-76
Author(s):  
D. V. Kabakov ◽  
S. V. Kiselev ◽  
E. A. Seregina ◽  
G. V. Tikhonov
Keyword(s):  
Chemical Yield ◽  
Radiation Chemical Yield ◽  
Radiation Chemical

Spectrum, Kinetics, and Radiation Chemical Yield of Solvated Electrons in Hexamethylphosphoric Triamide

1973 ◽  
Vol 51 (23) ◽  
pp. 3905-3913 ◽  
Author(s):  
Eric A. Shaede ◽  
Leon M. Dorfman ◽  
Garry J. Flynn ◽  
David C. Walker
Keyword(s):  
Pulse Radiolysis ◽  
Chemical Yield ◽  
Molar Absorptivity ◽  
Solvated Electrons ◽  
Experimental Conditions ◽  
Hexamethylphosphoric Triamide ◽  
Radiation Chemical ◽  
Optical Absorption Band ◽  
Bromide Ion ◽  
Kinetics Of

The spectrum, yield, and kinetics of solvated electrons in hexamethylphosphoric triamide were investigated by the pulse radiolysis method. The optical absorption band is in the infrared with a maximum at 2200 ± 100 nm. The molar absorptivity at this maximum is (3.2 ± 0.5) × 104 M−1 cm−1, and the oscillator strength for the transition is estimated to be f = 0.7 ± 0.2. A free ion yield of G(es−) = 2.3 + 0.4 solvated electrons/100 eV was determined from the observed yields of anthracene and pyrene radical anions formed by electron attachment.Kinetic studies provided values of the rate constants for the reaction of solvated electrons with anthracene and N2O. The decay mechanism of the solvated electrons in the absence of added solutes was found to be complex, and the half-life (in the range of 2 to 50 μs) was dependent on experimental conditions. A second transient species, absorbing at wavelengths below 500 nm, was observed but not identified. In solutions containing bromide ion the species Br2− was observed. The pulse radiolysis of stable solutions of es−, formed by dissolving sodium metal in HMPA, is also reported.

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