Critical Opalescence of Binary Liquid Mixtures. The Debye Molecular Interaction Range

1965 ◽  
Vol 69 (7) ◽  
pp. 2329-2332 ◽  
Author(s):  
B. Chu
2009 ◽  
Vol 6 (4) ◽  
pp. 1150-1152 ◽  
Author(s):  
R. Uvarani ◽  
J. Sivapragasam

Molecular interaction studies using ultrasonic technique in the binary liquid mixtures of cyclohexanone witho-cresol andp-cresol have been carried out at 303 K. Using the measured values of ultrasonic velocity, density and viscosity, acoustical parameters and their excess values are evaluated. From the properties of these excess parameters the nature and strength of the interactions in these binary systems are discussed.


ChemInform ◽  
2009 ◽  
Vol 40 (40) ◽  
Author(s):  
Bojan D. Djordjevic ◽  
Ivona R. Radovic ◽  
Mirjana L. J. Kijevcanin ◽  
Aleksandar Z. Tasic ◽  
Slobodan P. Serbanovic

Author(s):  
N. Santhi ◽  
P.L. Sabarathinam ◽  
J. Madhumitha ◽  
G. Alamelumangai ◽  
M. Emayavaramban

Ultrasonic velocities and densities of the binary liquid mixtures of benzene with 1-propanol, 2-propanol, 1-butanol, 2-butanol and 3-butanol at 303.15 to 318.15 K, over the entire composition range were measured. The theoretical values of ultrasonic velocity were evaluated using the Nomoto’s Relation (NR), Ideal Mixture Relation (IMR), Free Length Theory (FLT) and Collision Factor Theory (CFT). The validity of these relations and theories were tested by comparing the computed sound velocities with experimental values. Further, the molecular interaction parameter (α) was computed by using the experimental and the theoretical ultrasonic velocity values. The variation of this parameter with composition of the mixtures has been discussed in terms of molecular interaction in these mixtures.


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