Application of Irreversible Thermodynamics to Electrolyte Solutions. I. Determination of Ionic Transport Coefficients lijfor Isothermal Vector Transport Processes in Binary Electrolyte Systems1,2

1966 ◽  
Vol 70 (8) ◽  
pp. 2639-2659 ◽  
Author(s):  
Donald G. Miller
Keyword(s):  
Transport Coefficients ◽  
Ionic Transport ◽  
Electrolyte Solutions ◽  
Irreversible Thermodynamics ◽  
Transport Processes ◽  
Vector Transport

Determination of transport constants of isolated Nitella cell walls

1968 ◽  
Vol 46 (4) ◽  
pp. 317-327 ◽  
Author(s):  
M. T. Tyree
Keyword(s):  
Activation Energy ◽  
Cell Wall ◽  
Diffusion Coefficient ◽  
Cell Walls ◽  
Transport Coefficients ◽  
Irreversible Thermodynamics ◽  
Kcal Mole ◽  
Limiting Value ◽  
Nitella Flexilis

Transport coefficients LPP, LPE, LEP, and LEE for electrokinetic equations according to irreversible thermodynamics, the Onsager coefficients, were measured for isolated Nitella flexilis cell walls in KCl solutions ranging from 10−4 to 100 normal. LPP and LPE (= LEP) were found to be independent of KCl concentration and equal to 1.4 × 10−6 cm3 sec−1 cm−2 (joule cm−3)−1 cm and 6 × 10−5 cm3 sec−1 cm−2 volt−1 cm respectively. LEE was a function of the salt concentration, reaching a limiting value of about 1.2 × 10−3 mho cm−1 in 10−4 N KCl. The activation energy for movement of KCl in cell walls was found to be 4.33 Kcal mole−1; the diffusion coefficient for KCl in cell walls was calculated by two methods to be 8 × 10−6 cm2 sec−1; and the concentration of the fixed ions in Nitella cell walls from the above data was estimated at greater than 0.04 equivalent per liter of cell wall. Electroosmosis in Nitella membranes is re-examined in the light of the measured transport coefficients and it is concluded that under proper conditions the cell wall of Nitella can contribute significantly (~20% or more) to the observed electroosmosis of living Nitella cells.

Bicarbonate and CO2 transport across the skin of the leopard frog, Rana pipiens: effect of PGF2alpha

1997 ◽  
Vol 272 (2) ◽  
pp. R640-R647 ◽  
Author(s):  
O. A. Candia ◽  
T. Yorio
Keyword(s):  
Methodological Approach ◽  
Transport Processes ◽  
Leopard Frog ◽  
Bicarbonate Transport ◽  
Amphibian Skin ◽  
Acid Base ◽  
Reliable Determination ◽  
Net Flux ◽  
Unidirectional Fluxes

The amphibian skin represents an important organ for osmoregulation and, like the mammalian kidney, maintains acid-base balance by secreting protons or base. However, the lack of a reliable and accurate method to measure the contribution of unidirectional fluxes of HCO3- ions to this mechanism has been an obstacle for the determination of the role of bicarbonate in epithelial acid-base homeostasis. Recently, one of us developed a method that allows for the reliable determination of transepithelial fluxes of bicarbonate, and this method was applied to determine unidirectional fluxes of (14)CO2 and H(14)CO3 under a variety of conditions. We report that the combined CO2 and HCO3- mucosal-to-serosal flux under 5% CO2 was 40% larger than the opposing flux, giving a net flux in the mucosal-to-serosal direction. This net flux was inhibited by acetazolamide. In CO2-free conditions, there was no detectable net flux; however, acetazolamide and PGF(2alpha) attenuated the mucosal-to-serosal flux and established an apparent secretion of HCO3-. A model is presented that depicts twelve vectors or components to the CO2 plus HCO3- fluxes in the frog skin. This model can accurately reproduce the experimental values measured from unidirectional fluxes of CO2 and HCO3- under a variety of conditions and can explain the effects of PGF(2alpha) on unidirectional 14C-labeled fluxes as a consequence of inhibition of H+ secretion to the apical bath, similar to what was previously suggested by our laboratory using a different methodological approach. The present method, utilizing radiolabeled HCO3-, may be useful as a means to evaluate the mechanism of action of hormones and drugs that may regulate acid-base homeostasis by altering proton and bicarbonate transport processes.

Determination of Krafft point and CMC of hexadecylpyridinium salts in electrolyte solutions

1987 ◽  
Vol 120 (1) ◽  
pp. 114-117 ◽  
Author(s):  
Klaus Heckmann ◽  
Reinhard Schwarz ◽  
Jiri Strnad
Keyword(s):  
Electrolyte Solutions ◽  
Krafft Point

Anomalous transport coefficients in a magnetized turbulent plasma

1982 ◽  
Vol 28 (2) ◽  
pp. 193-214 ◽  
Author(s):  
Qiu Xiaoming ◽  
R. Balescu
Keyword(s):  
Transport Coefficients ◽  
Collision Operator ◽  
Turbulent Plasma ◽  
Anomalous Transport ◽  
Weak Turbulence ◽  
Dissipative Effects ◽  
Dependent Transport ◽  
Two Fluid ◽  
Two Fluid Plasma

In this paper we generalize the formalism developed by Balescu and Paiva-Veretennicoff, valid for any kind of weak turbulence, for the determination of all the transport coefficients of an unmagnetized turbulent plasma, to the case of a magnetized one, and suggest a technique to avoid finding the inverse of the turbulent collision operator. The implicit plasmadynamical equations of a two-fluid plasma are presented by means of plasmadynamical variables. The anomalous transport coefficients appear in their natural places in these equations. It is shown that the necessary number of transport coefficients for describing macroscopically the magnetized turbulent plasma does not exceed the number for the unmagnetized one. The typical turbulent and gyromotion terms, representing dissipative effects peculiar to the magnetized system, which contribute to the frequency-dependent transport coefficients are clearly exhibited.

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