Electron Spin Resonance Spectrum and Electronic Structure of the PO32-Radical in an X-Ray Irradiated Single Crystal of Ammonium Fluorophosphate

1966 ◽  
Vol 70 (8) ◽  
pp. 2487-2492 ◽  
Author(s):  
F. G. Herring ◽  
J. H. Hwang ◽  
W. C. Lin ◽  
C. A. McDowell
Keyword(s):  
Electronic Structure ◽  
Electron Spin Resonance ◽  
Single Crystal ◽  
Electron Spin Resonance Spectrum ◽  
Electron Spin ◽  
Resonance Spectrum ◽  
X Ray ◽  
Spin Resonance

ESR of Gamma Irradiated KHSO4 Single Crystal

1975 ◽  
Vol 30 (6-7) ◽  
pp. 750-753
Author(s):  
F. Köksal ◽  
H. Yüksel
Keyword(s):  
Electron Spin Resonance ◽  
Single Crystal ◽  
Electron Spin Resonance Spectrum ◽  
Electron Spin ◽  
Resonance Spectrum ◽  
Paramagnetic Species ◽  
G Factor ◽  
Spin Resonance ◽  
Potassium Hydrogen ◽  
Gamma Irradiated

Abstract Potassium hydrogen sulphate single crystal has been γ-irradiated at room temperature and its electron spin resonance spectrum recorded by changing the H0 static magnetic field, around an orthogonal axes system. The electron spin resonance spectrum is a single line with a slightly anisotropic g factor. The paramagnetic species has been identified as SO3- and the principal values of the g tensor has been determined as g1=g2=2.0060, g3 = 2.0045. Direction cosines of the principalvalues of the g tensor with respect to the chosen axes have been determined. The spin-orbit contribution to the g-factor has been explained.

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