Phase equilibria in solutions of liquid sulfur. II. Experimental studies in ten solvents: carbon disulfide, carbon tetrachloride, benzene, toluene, o-xylene, naphthalene, biphenyl, triphenylmethane, cis-Decalin, and Trans-Decalin

1967 ◽  
Vol 71 (2) ◽  
pp. 352-358 ◽  
Author(s):  
John A. Larkin ◽  
Jeffrey Katz ◽  
Robert Lane Scott
Keyword(s):  
Carbon Tetrachloride ◽  
Phase Equilibria ◽  
Carbon Disulfide ◽  
Experimental Studies ◽  
Liquid Sulfur ◽  
Benzene Toluene

scholarly journals High-Frequency Polarographic Microdetermination of Carbon Disulfide in Carbon Tetrachloride

1967 ◽  
Vol 88 (6) ◽  
pp. 644-647 ◽  
Author(s):  
Tomihito KAMBARA ◽  
Shigeyuki TANAKA ◽  
Kiyoshi HASEBE
Keyword(s):  
Carbon Tetrachloride ◽  
Carbon Disulfide ◽  
High Frequency

COMPLEXES OF STANNIC IODIDE WITH AROMATIC HYDROCARBONS

1965 ◽  
Vol 43 (5) ◽  
pp. 1272-1278 ◽  
Author(s):  
J. F. Murphy ◽  
D. E. Baker
Keyword(s):  
Carbon Tetrachloride ◽  
Complex Formation ◽  
Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbons ◽  
Extinction Coefficient ◽  
Regular Solutions ◽  
Benzene Toluene ◽  
Yield Values ◽  
Complex Stabilities ◽  
Iodide Complex

Spectrophotometric measurements on solutions of stannic iodide were found to provide evidence for complex formation with aromatic hydrocarbons. Calculations, based on spectra for mixed solutions of benzene and stannic iodide in carbon tetrachloride, yield values of 0.26 for the equilibrium constant (mole fraction), 28 400 1/mole cm for the molar extinction coefficient of the benzene – stannic iodide complex. Kinetic evidence indicates that the order of decreasing complex stabilities is from xylene to toluene to benzene. The formation of stannic iodide – aromatic hydrocarbon complexes provides an explanation for the discrepancy between measured solubilities of stannic iodide in benzene, toluene, and xylene, and the solubilities predicted by the Hildebrand theory of regular solutions.

Influence of pressure on the thermodynamic properties of simple molecular fluids: carbon tetrachloride + carbon disulfide system

1988 ◽  
Vol 92 (13) ◽  
pp. 3998-4006 ◽  
Author(s):  
A. Compostizo ◽  
A. Crespo Colin ◽  
M. R. Vigil ◽  
R. G. Rubio ◽  
M. Diaz Pena
Keyword(s):  
Carbon Tetrachloride ◽  
Thermodynamic Properties ◽  
Carbon Disulfide ◽  
Molecular Fluids

scholarly journals Carbides and Nitrides of Zirconium and Hafnium

Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2728 ◽  
Author(s):  
Sergey V. Ushakov ◽  
Alexandra Navrotsky ◽  
Qi-Jun Hong ◽  
Axel van de Walle
Keyword(s):  
Experimental Data ◽  
Phase Equilibria ◽  
Ab Initio ◽  
Solid Solutions ◽  
Binary Systems ◽  
Experimental Studies ◽  
Published Data ◽  
Oxygen Solubility ◽  
Melting Temperatures ◽  
Ab Initio Computations

Among transition metal carbides and nitrides, zirconium, and hafnium compounds are the most stable and have the highest melting temperatures. Here we review published data on phases and phase equilibria in Hf-Zr-C-N-O system, from experiment and ab initio computations with focus on rocksalt Zr and Hf carbides and nitrides, their solid solutions and oxygen solubility limits. The systematic experimental studies on phase equilibria and thermodynamics were performed mainly 40–60 years ago, mostly for binary systems of Zr and Hf with C and N. Since then, synthesis of several oxynitrides was reported in the fluorite-derivative type of structures, of orthorhombic and cubic higher nitrides Zr3N4 and Hf3N4. An ever-increasing stream of data is provided by ab initio computations, and one of the testable predictions is that the rocksalt HfC0.75N0.22 phase would have the highest known melting temperature. Experimental data on melting temperatures of hafnium carbonitrides are absent, but minimum in heat capacity and maximum in hardness were reported for Hf(C,N) solid solutions. New methods, such as electrical pulse heating and laser melting, can fill the gaps in experimental data and validate ab initio predictions.

SYNERGISTIC NEUROTOXICITY OF CARBON TETRACHLORIDE/CARBON DISULFIDE (80/20 FUMIGANTS) AND OTHER PESTICIDES IN GRAIN STORAGE WORKERS

2009 ◽  
Vol 59 ◽  
pp. 535-546 ◽  
Author(s):  
Henry A. Peters ◽  
Ross L. Levine ◽  
Charles G. Matthews ◽  
Steve Sauter ◽  
Larry Chapman
Keyword(s):  
Carbon Tetrachloride ◽  
Carbon Disulfide ◽  
Grain Storage

Analysis of Commercially Fumigated Grains for Residues of Organic Fumigants

1971 ◽  
Vol 54 (4) ◽  
pp. 964-965
Author(s):  
Bernadette Malone McMahon
Keyword(s):  
Liquid Chromatography ◽  
Carbon Tetrachloride ◽  
Carbon Disulfide ◽  
Acid Reflux ◽  
Gas Liquid Chromatography ◽  
Ethylene Dibromide ◽  
Residue Levels ◽  
Storage Bins

Abstract Seven lots of commercially fumigated grains were sampled from storage bins and analyzed for residues of the organic fumigants. Residues were isolated by the acid reflux procedure and determined by gas-liquid chromatography. Residue levels ranged from 0.84 to 2.16 ppm carbon disulfide, 2.92 to 20.4 ppm carbon tetrachloride, and <0.01 to 6.10 ppm ethylene dibromide. In general, residue levels found on grains fumigated at different times indicated the tendency for the volatile fumigants to dissipate with time. The lower volatility of ethylene dibromide results in disproportionately high residues compared to carbon disulfide and carbon tetrachloride, which were applied at higher rates.

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