Thermodynamic treatment and electromotive force measurements of the ternary molten salt systems silver chloride-sodium chloride-potassium chloride and silver chloride-sodium chloride-cesium chloride

1968 ◽  
Vol 72 (6) ◽  
pp. 2086-2095 ◽  
Author(s):  
J. Guion ◽  
M. Blander ◽  
D. Hengstenberg ◽  
K. Hagemark
Keyword(s):  
Sodium Chloride ◽  
Potassium Chloride ◽  
Molten Salt ◽  
Electromotive Force ◽  
Silver Chloride ◽  
Cesium Chloride ◽  
Force Measurements ◽  
Electromotive Force Measurements ◽  
Salt Systems

Potentiométrie de précision à basse température dans les mélanges eau – éthylène glycol; grandeurs thermodynamiques relatives aux ionisations de l'acide acétique et du solvant mixte

1983 ◽  
Vol 61 (10) ◽  
pp. 2344-2348 ◽  
Author(s):  
Hamed Bahri ◽  
Jean-Claude Hallé ◽  
Robert Schaal
Keyword(s):  
Ethylene Glycol ◽  
Electromotive Force ◽  
Dissociation Constants ◽  
Silver Chloride ◽  
Force Measurements ◽  
Liquid Junction ◽  
Solvent Water ◽  
Electromotive Force Measurements ◽  
Silver Silver ◽  
Silver Silver Chloride

Electromotive force measurements of cells without liquid-junction containing hydrogen electrodes and silver – silver chloride electrodes have been used to derive the dissociation constants of acetic acid and solvent water – ethylene glycol mixtures (50 and 70 mass % of ethyleneglycol) at 14 temperatures from −35 to 30 °C. Primary acidity standards related to these acetic buffered and sodium hydroxide solutions are given.

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