Study of ion-solvent interaction of some tetraalkylammonium and common ions in N-methylacetamide from apparent molal volume data

1969 ◽  
Vol 73 (10) ◽  
pp. 3390-3394 ◽  
Author(s):  
Ram Gopal ◽  
Mohammed Aslam Siddiqi
Keyword(s):  
Apparent Molal Volume ◽  
Volume Data ◽  
Molal Volume ◽  
Solvent Interaction

Ultrasonic and Density Studies of D(+) Mannose with Aqueous Electrolytes at 303K

2014 ◽  
Vol 1051 ◽  
pp. 215-220 ◽  
Author(s):  
Yasmin Akhtar
Keyword(s):  
Adiabatic Compressibility ◽  
Ternary Systems ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Solvent Interactions ◽  
Alkali Metal Halides ◽  
Experimental Values ◽  
Apparent Molal Adiabatic Compressibility

The present experimental investigation was carried out in order to explore the possible molecular interactions of D(+) mannose with mixed solvent of aqueous NaCl, KCl , MgCl2and CaCl2at 303 K. Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+) mannose with aqueous NaCl ,KCl, MgCl2and CaCl2. Aqueous alkali metal halides (NaCl ,KCl , MgCl2and CaCl2) were added under different molalities with D(+) mannose. The related and relevant parameters correlated to the present study such as adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0vand partial molal adiabatic compressibility, фoKsat infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion, ion-solvent, solute-solute and solute-solvent interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.

scholarly journals Acoustic and Volumetric Properties of Digoxin and Thiabendazole in 1, 4 Dioxane at 303 K

2010 ◽  
Vol 7 (3) ◽  
pp. 789-794 ◽  
Author(s):  
A. N. Sonar ◽  
N. S. Pawar
Keyword(s):  
Adiabatic Compressibility ◽  
Viscosity Coefficient ◽  
Volumetric Properties ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Acoustical Parameter ◽  
Solute Interaction ◽  
Apparent Molal Compressibility

Acoustical and volumetric properties have been measured for substituted heterocyclic compounds digoxin and thiabendazole in 1, 4 dioxane at 303 K. The ultrasonic velocity measurement have been performed to evaluate acoustical parameter such as adiabatic compressibility (βs), partial molal volume (ɸv), intermolecular free length (Lf), apparent molal compressibility (ɸk), specific acoustic impedance (Z), relative association (RA), salvation number (Sn), limiting apparent molal compressibility (ɸ0k), limiting apparent molal volume(ɸ0v) and their constant (Sk,Sv). The viscosity coefficient (A, B) was evaluated by using john–dole equation. These parameters throw the light on the solute-solvent interaction and solute-solute interaction.

scholarly journals Volumetric Properties of Secondary Butanol and Tertiary Butanol in Water and Aqueous Micellar Systems of Sodium Dodecyl Sulphate

2020 ◽  
Vol 12 (3) ◽  
pp. 419-429
Author(s):  
J. Alauddin ◽  
S. Pande ◽  
S. C. Mohanta ◽  
M. Alauddin
Keyword(s):  
Sodium Dodecyl Sulphate ◽  
Sodium Dodecyl ◽  
Water System ◽  
Apparent Molal Volume ◽  
Micellar System ◽  
Volume Data ◽  
Molal Volume ◽  
Apparent Molal Volumes ◽  
Aqueous Solvent ◽  
Molal Volumes

The apparent molal volumes of sec-butanol and t-butanol in water and in aqueous micellar system of sodium dodecyl sulphate have been determined from density measurements at different surfactant concentrations and temperatures. The partial molal volumes of the alcohols in aqueous micellar system at infinite dilution, V20 (mean, mic) were obtained from apparent molal volume data and compared with the corresponding values in aqueous solvent, V20  (mean, aq). The standard partial molal expansibilities, E20 (mean) of the alcohols were evaluated from V20 (mean) data at various temperatures. The transfer apparent molal volumes, ∆φtr0 for the alcohols from water to surfactant-water system are determined from apparent molal volume data. The sign and magnitude of these parameters are used to analyze the location of the solubilizate (alcohols) in the micellar system and the nature of interactions between alcohols and the micellar aggregates.

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