KINETICS OF THE REACTIONS OF SODIUM CYANIDE WITH SOME ALKYL IODIDES

1960 ◽  
Vol 64 (11) ◽  
pp. 1719-1720 ◽  
Author(s):  
K. R. Lynn ◽  
Peter E. Yankwich
Keyword(s):  
Sodium Cyanide ◽  
Alkyl Iodides ◽  
Kinetics Of

Atmospheric chemistry of alkyl iodides: theoretical studies on the mechanisms and kinetics of CH3I/C2H5I + NO3 reactions

RSC Advances ◽  
2015 ◽  
Vol 5 (107) ◽  
pp. 88087-88095 ◽  
Author(s):  
Feng-Yang Bai ◽  
Xu Wang ◽  
Yan-Qiu Sun ◽  
Xiu-Mei Pan
Keyword(s):  
Atmospheric Chemistry ◽  
Theoretical Basis ◽  
Theoretical Studies ◽  
Alkyl Iodides ◽  
Kinetics Of ◽  
Sound Theoretical Basis

Mechanisms and kinetics of the reactions of the NO3 radical with CH3I and C2H5I have been investigated from a sound theoretical basis.

Kinetics of isotopic exchange reactions of alkyl iodides

1958 ◽  
Vol 45 (7) ◽  
pp. 163-163
Author(s):  
D. G�l ◽  
F. Dutka
Keyword(s):  
Isotopic Exchange ◽  
Exchange Reactions ◽  
Alkyl Iodides ◽  
Kinetics Of

Anti-Cyanide Drugs: Kinetics of the Removal of Copper(II) and Nickel(II) from N-Methyl-tetra(4-sulfonatophenyl)porphyrins by Cyanide. LD50s of Common Metalloporphyrins and Metallophthalocyanines

1998 ◽  
Vol 02 (06) ◽  
pp. 493-499 ◽  
Author(s):  
R. RAHIMI ◽  
P. HAMBRIGHT
Keyword(s):  
Metal Ions ◽  
Hydrogen Cyanide ◽  
Metal Removal ◽  
Equilibrium Constants ◽  
Sodium Cyanide ◽  
Water Soluble ◽  
Rate Laws ◽  
Kinetics Of

The purpose of this project was to develop prophylactic water-soluble anti-cyanide drugs. The 24 h mean LD 50s in mice of 13 common metalloporphyrins and metallophthalocyanines are reported. At doses of 1/4, 1/16 and 1/64 of the LD 50 administered 15 or 60 min prior to a 2LD50 challenge of sodium cyanide, none of these compounds protected mice against cyanide. While Co ( H 2 O )6 Cl 2 and Ni ( H 2 O )6Cl2 were found to be effective, they are too toxic to be useful. A stable metalloporphyrin that could scavenge cyanide by donating metal ions to produce non-toxic polycyano species in the presence of cyanide would be desirable. We found that nickel(II) and copper(II) are removed from their N-methyl-tetra(4-sulfonato)porphyrins by cyanide and hydrogen cyanide. These reactions are not observed with the parent tetra(4-sulfonatophenyl)porphyrins. Equilibrium constants for cyanide addition to both types of metalloporphyrins and the rate laws for metal removal by cyanide and HCN are reported. The medical implications of these findings are discussed.

Kinetics of the Reactions of Alkyl Iodides with HI

1961 ◽  
Vol 34 (2) ◽  
pp. 514-520 ◽  
Author(s):  
Sidney W. Benson ◽  
Edward O'Neal
Keyword(s):  
Alkyl Iodides ◽  
Kinetics Of
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