COMMENTS ON THE MECHANISM OF THE REACTION OF ACTIVE NITROGEN WITH ETHYLENE AND NITRIC OXIDE

1960 ◽  
Vol 64 (9) ◽  
pp. 1343-1344 ◽  
Author(s):  
Walter G. Zinman
Keyword(s):  
Nitric Oxide ◽  
Active Nitrogen ◽  
Mechanism Of The Reaction

Nitrogen-15 tracer investigation of the mechanism of the reaction of nitric oxide with ammonia on vanadium oxide catalysts

1982 ◽  
Vol 86 (15) ◽  
pp. 2945-2950 ◽  
Author(s):  
Akira Miyamoto ◽  
Kan Kobayashi ◽  
Makoto Inomata ◽  
Yuichi Murakami
Keyword(s):  
Nitric Oxide ◽  
Vanadium Oxide ◽  
Oxide Catalysts ◽  
Mechanism Of The Reaction

Stabile und instabile Produkte bei der Reaktion von 2.2-Diphenyl-1,2-dihydrochinolinnitroxid-Radikalen mit Stickstoffmonoxid / Stable and Unstable Products on the Reaction of 2.2-Diphenyl-1,2-dihydroquinolinenitroxide Radicals with Nitric Oxide

1994 ◽  
Vol 49 (8) ◽  
pp. 1041-1050 ◽  
Author(s):  
Horst Weber ◽  
Andreas Grzesiok ◽  
Reiner Sustmann ◽  
Hans-Gert Korth
Keyword(s):  
Nitric Oxide ◽  
Nitro Compounds ◽  
Nitroso Compounds ◽  
Mechanism Of The Reaction

The stable 2,2-diphenyl-1,2-dihydroquinolinenitroxide radicals 1 react with nitric oxide (NO) to form the stable nitro compounds 2 and 3 as main products. The stable dinitro compounds 6 and 1,2-dihydroquinolines 7 are formed in minor yield as side-products accom­panied with the unstable N-nitroso compounds 4 and 5, which further decompose to form the stable products mentioned above. The proposed mechanism of the reaction is discussed in terms of homolytical processes and is supported by PM 3 calculations.

THE KINETICS OF THE REACTION OF ACTIVE NITROGEN WITH ETHYLENE

1962 ◽  
Vol 40 (4) ◽  
pp. 686-691 ◽  
Author(s):  
E. M. Levy ◽  
C. A. Winkler
Keyword(s):  
Nitric Oxide ◽  
Activation Energy ◽  
Low Temperature ◽  
Copper Oxide ◽  
Cobalt Catalyst ◽  
Cobalt Catalysts ◽  
Active Nitrogen ◽  
Temperature Range ◽  
P Factor ◽  
Kinetics Of

A comparison has been made of five methods for terminating the reaction of active nitrogen with ethylene in the temperature range 295° to 673° K. These were based on deactivating the active nitrogen by low-temperature trapping, by addition of nitric oxide, and by passing it over copper oxide or cobalt catalysts. With the nitric oxide and cobalt catalyst techniques, which appeared to be the most reliable of those used, an activation energy of 400 ± 200 cal/mole, with a P factor of about 10−5, have been determined for the reaction.

scholarly journals A chemically active modification of nitrogen, produced by the electric discharge.—VI

1915 ◽  
Vol 91 (628) ◽  
pp. 303-318 ◽  
Keyword(s):  
Nitric Oxide ◽  
Electric Discharge ◽  
Pure Nitrogen ◽  
Active Nitrogen ◽  
Considerable Controversy

1. Effect of Catalysts in Promoting the Formation of Active Nitrogen . There has been considerable controversy on the question of whether or not pure nitrogen would give the afterglow, which, as I have shown in the previous papers of this series, is associated with the presence of chemically active nitrogen. E. P Lewis was disposed to think that the presence of oxygen or nitric oxide was essential, but in a much later paper, though still inclined to the same opinion, he states that the afterglow continually increased in intensity as the proportion of oxygen was reduced.

Sign in / Sign up

Export Citation Format

Share Document