ASSOCIATION EQUILIBRIA AND COMPOUND FORMATION IN THE PHOSPHORUS TRICHLORIDE-TRIMETHYLAMINE SYSTEM

1960 ◽  
Vol 64 (9) ◽  
pp. 1295-1299 ◽  
Author(s):  
Robert R. Holmes
Keyword(s):  
Phosphorus Trichloride ◽  
Compound Formation ◽  
Association Equilibria

An Electron Microscope Study of Interdiffusion and Compound Formation in Ta-Au Thin Films

1973 ◽  
Vol 31 ◽  
pp. 32-33 ◽  
Author(s):  
T. C. Tisone ◽  
S. Lau
Keyword(s):  
Electron Microscope ◽  
Electron Microscope Study ◽  
Thermally Grown Oxide ◽  
Ion Milling ◽  
Compound Formation ◽  
Technology Application ◽  
Transmission Electron ◽  
Before And After ◽  
Au Thin Films

In a study of the properties of a Ta-Au metallization system for thin film technology application, the interdiffusion between Ta(bcc)-Au, βTa-Au and Ta2M-Au films was studied. Considered here is a discussion of the use of the transmission electron microscope(TEM) in the identification of phases formed and characterization of the film microstructures before and after annealing.The films were deposited by sputtering onto silicon wafers with 5000 Å of thermally grown oxide. The film thicknesses were 2000 Å of Ta and 2000 Å of Au. Samples for TEM observation were prepared by ultrasonically cutting 3mm disks from the wafers. The disks were first chemically etched from the silicon side using a HNO3 :HF(19:5) solution followed by ion milling to perforation of the Au side.

Modern Greek V V dvandva compounds: A linguistic innovation in the history of the Indo-European languages

2009 ◽  
Vol 2 (1) ◽  
pp. 48-68 ◽  
Author(s):  
Angela Ralli
Keyword(s):  
Language Contact ◽  
High Rate ◽  
Compound Formation ◽  
Modern Greek ◽  
Late Medieval Period ◽  
European Languages ◽  
History Of ◽  
Internal Change ◽  
Contact Situation ◽  
Asian Languages

This paper deals with [V V] dvandva compounds, which are frequently used in East and Southeast Asian languages but also in Greek and its dialects: Greek is in this respect uncommon among Indo-European languages. It examines the appearance of this type of compounding in Greek by tracing its development in the late Medieval period, and detects a high rate of productivity in most Modern Greek dialects. It argues that the emergence of the [V V] dvandva pattern is not due to areal pressure or to a language-contact situation, but it is induced by a language internal change. It associates this change with the rise of productivity of compounding in general, and the expansion of verbal compounds in particular. It also suggests that the change contributes to making the compound-formation patterns of the language more uniform and systematic. Claims and proposals are illustrated with data from Standard Modern Greek and its dialects. It is shown that dialectal evidence is crucial for the study of the rise and productivity of [V V] dvandva compounds, since changes are not usually portrayed in the standard language.

Interionic Pair Potential, hard sphere diameter and entropy of mixing of NaCd compound forming binary molten alloys under the framework of Pseudopotential theory

2014 ◽  
Vol 10 (6) ◽  
pp. 2843-2852
Author(s):  
Sujeet Kumar Chatterjee ◽  
Lokesh Chandra Prasad ◽  
Ajaya Bhattarai
Keyword(s):  
Nearest Neighbor ◽  
Effective Interaction ◽  
Pair Potential ◽  
Sphere Diameter ◽  
Compound Formation ◽  
Pseudopotential Theory ◽  
Energy Of Mixing ◽  
Asymmetric Behaviour ◽  
Statistical Mechanical ◽  
Free Energy Of Mixing

The observed asymmetric behaviour of mixing of  NaCd liquid alloys around equiatomic composition with smaller negative values for free energy of mixing at compound forming concentration, i.e. GMXS = -4.9KJ at Ccd =0.66 has  aroused our interest to undertake a theoretical investigation of this system.A simple statistical mechanical theory based on compound formation model has been used to investigate the energetics of formation of intermetallic compound Cd2Na in the melt through the study of entropy of mixing.Besides, the interionic interactions between component atoms Na and Cd of the alloys have been understood through the study of interionic pair potential фij(r), calculated from pseudopotential theory in the light of CF model.Our study of фij(r) suggest that the effective interaction between Na-Na atoms decreases on alloying with Cd atom, being minimum for compound forming alloy( Cd 0.66 Na 0.34 ).The nearest neighbor distance between Na-Na atoms does not alter on alloying. Like wise Na-Na,  effective interaction between  Cd-Cd atom decreases from pure state to NaCd alloys, being smaller at compound forming  concentration Cd 0.66 Na 0.34.The computed values of SM from pseudopotential theory are positive at all concentrations, but the agreement between theory and experimental is not satisfactory. This might be happening due to parameterisation of σ3 and Ψcompound.

The phase instability and critical point in a liquid mixture of an associating and inert component

1979 ◽  
Vol 44 (12) ◽  
pp. 3574-3587
Author(s):  
Julius Pouchlý ◽  
Antonín Sikora
Keyword(s):  
Binary System ◽  
Critical Point ◽  
Multicomponent Mixture ◽  
Liquid Mixture ◽  
Inert Component ◽  
Phase Instability ◽  
Complex Species ◽  
Total Composition ◽  
Association Equilibria ◽  
The Individual

The problem of phase instability in a binary mixture of an associating component with an inert component is analyzed from the standpoint of the theory of association equilibria. It is demonstrated that conditions of the spinodal and critical point for such a binary system are equivalent to those of the spinodal and critical point of a multicomponent mixture consisting of complex species arising by association (including nonassociated molecules). These conditions are formulated so as if species in this mixture did not participate in association and dissociation processes; configurational terms expressing changes in the content of the individual complexes depending on changes in total composition are included implicitly.

Effect of adding Ag to the medium entropy SnBiIn alloy on intermetallic compound formation

2020 ◽  
Vol 272 ◽  
pp. 127891 ◽  
Author(s):  
Li Pu ◽  
Yingxia Liu ◽  
Yong Yang ◽  
Quanfeng He ◽  
Ziqing Zhou ◽  
...  
Keyword(s):  
Intermetallic Compound ◽  
Compound Formation ◽  
Intermetallic Compound Formation
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