A COMPARATIVE STUDY OF THE DECAR-BOXYLATION OF MALONIC ACID AND OXANILIC ACID IN ETHERS AND IN TERTIARY AMINES

1961 ◽  
Vol 65 (12) ◽  
pp. 2271-2272 ◽  
Author(s):  
Louis Watts Clark
2008 ◽  
Vol 12 (12) ◽  
pp. 1223-1231 ◽  
Author(s):  
Sébastien Balieu ◽  
Zakaria Halime ◽  
Mohammed Lachkar ◽  
Bernard Boitrel

A comparative study of bismuth complexation by various porphyrins which differ according to the structural scaffold – either picket(s) or strap(s) – that deliver the carboxylic acid groups close to the metal, has been performed. Unlike strapped porphyrins, and although more flexible, the picket ligands do not lead to more stable bismuth complexes.


1994 ◽  
Vol 224 (3-4) ◽  
pp. 333-337 ◽  
Author(s):  
H. Klos ◽  
I. Rystau ◽  
W. Schütz ◽  
B. Gotschy ◽  
A. Skiebe ◽  
...  

A comparative study of the gaseous oxidation of N - methyl diethylamine and N -ethyl dimethylamine shows that the former compound closely resembles triethylamine in its general behaviour, while the latter compound exhibits a striking similarity to trimethylamine. With both the mixed tertiary amines a reaction occurs which leads to the formation of secondary amine, but which rapidly becomes self-inhibited as oxidation proceeds. Only with N -methyl dimethylamine, however, are substantial amounts of primary amine formed among the products of slow combustion. A possible explanation of this last difference is that only peroxy-radicals derived from tertiary amines containing at least two ethyl groups can, on steric grounds, readily undergo intramolecular attack to yield monoalkylamines. The apparent ease of such a reaction during the oxidation of N -methyl diethylamine and triethylamine may thus account for the marked contrast between the behaviour of these two compounds on the one hand and that of N -ethyl dimethylamine and trimethylamine on the other.


2020 ◽  
Author(s):  
Bruno Oliveira Ferreira de Souza ◽  
Éve‐Marie Frigon ◽  
Robert Tremblay‐Laliberté ◽  
Christian Casanova ◽  
Denis Boire

2001 ◽  
Vol 268 (6) ◽  
pp. 1739-1748
Author(s):  
Aitor Hierro ◽  
Jesus M. Arizmendi ◽  
Javier De Las Rivas ◽  
M. Angeles Urbaneja ◽  
Adelina Prado ◽  
...  

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