ELECTRON SPIN RESONANCE OF AROMATIC HYDROCARBONS ON SILICA—ALUMINA CATALYSTS

1961 ◽  
Vol 65 (10) ◽  
pp. 1919-1919 ◽  
Author(s):  
James K. Fogo
1970 ◽  
Vol 48 (12) ◽  
pp. 1942-1945 ◽  
Author(s):  
J. T. Cooper ◽  
W. F. Forbes ◽  
J. C. Robinson

The electron spin resonance spectra are presented for the anions and cations of the polynuclear aromatic hydrocarbons anthanthrene, benz[ghi]perylene, benz[e]pyrene, dibenz[fg,op]naphthacene, and dibenz[a,c]triphenylene. The cation of dibenz[fg,op]naphthacene is shown to form a dimer under certain conditions.The usefulness of a new oxidizing agent for the production of the cations, boron trichloride, has been investigated and was found to afford comparable spectra to boron trifluoride, using sulfur dioxide as solvent.


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