SOLUBILITY OF LEAD SULFATE AS A FUNCTION OF ACIDITY. THE DISSOCIATION OF BISULFATE ION

1961 ◽  
Vol 65 (2) ◽  
pp. 243-246 ◽  
Author(s):  
R. W. Ramette ◽  
R. F. Stewart
Keyword(s):  
2021 ◽  
Vol 296 ◽  
pp. 126512
Author(s):  
Lin Chen ◽  
Peng Chen ◽  
Zhenhu Wang ◽  
Weifeng Liu ◽  
Duchao Zhang ◽  
...  

1993 ◽  
Vol 42 (1-2) ◽  
pp. 55-70 ◽  
Author(s):  
L.T. Lam ◽  
H. Ozgun ◽  
L.M.D. Cranswick ◽  
D.A.J. Rand

2021 ◽  
Vol 316 ◽  
pp. 705-710
Author(s):  
A.G. Ryazanov ◽  
A.V. Senin ◽  
V.D. Nasonov

Waelz-oxide is a raw material for the production of metallic zinc. Waelz-oxide contains impurities of zinc and lead chlorides and fluorides. Halides have a negative effect on the process of zinc electrolysis. Halides have a relatively low boiling point; therefore, they are removed into the gas phase by calcining Waelz-oxide at 800–850 °С. To intensify the process, calcination is sometimes carried out at elevated temperatures of 1100–1250 °С. However, an increase in temperature leads to partial melting and granulation of the calcined product. In the present work, the chemical and phase composition of the initial and calcined Waelz-oxide was studied. Thermodynamic modeling of phase and chemical transformations of Waelz-oxide components during heating has been performed. Experiments on calcination of Waelz-oxide in laboratory conditions at temperatures of 600–1250 °C were carried out. It was found that partial melting and granulation of Waelz-oxide is the result of the formation of fusible eutectics containing lead oxide. Lead oxide is formed as a result of decomposition of lead sulfate when heated above 1100 °C. A similar effect is not observed at a standard calcination temperature of 850 °C.


1985 ◽  
Vol 16 (20) ◽  
Author(s):  
P. BOHER ◽  
B. F. MENTZEN ◽  
P. GARNIER ◽  
A. LATRACH
Keyword(s):  

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