COÖRDINATION COMPOUNDS. III. CHELATE COMPOUNDS OF THE URANYL ION WITH HYDROXY, MERCAPTO, AND AMINO ACIDS1

1962 ◽  
Vol 66 (5) ◽  
pp. 790-791 ◽  
Author(s):  
Michael Cefola ◽  
Robert C. Taylor ◽  
Philip S. Gentile ◽  
A. V. Celiano
Keyword(s):  
Coordination Compounds ◽  
Uranyl Ion ◽  
Chelate Compounds

scholarly journals New coordination compounds of uranyl ion with 3-(2-hydroxyphenyl)-1,2,4-triazole and its derivatives: synthesis and investigation of spectral properties

2015 ◽  
Vol 3 (2) ◽  
pp. 109-114 ◽  
Author(s):  
Oleksandr Vashchenko ◽  
Dmytro Khomenko ◽  
Roman Doroschuk ◽  
Rostyslav Lampeka
Keyword(s):  
Ir Spectroscopy ◽  
Coordination Compounds ◽  
Spectral Properties ◽  
Complex Compounds ◽  
Uranyl Ion ◽  
New Methods ◽  
Coordination Compounds Of Uranyl

New methods of 3-(2-hydroxyphenyl)-1,2,4-triazoles synthesis were developed. Obtained ligands was used for synthesis of three new complex compounds of uranyl-ion with general composition [UO2(HL)2(Solv)]. These compounds were characterized by NMR and IR spectroscopy.

Tridentate Chelate Compounds. V. Coordination Compounds Derived from Cobalt Salts and 1,3-Disubstituted 1,2-Diaza-2-propenes

1964 ◽  
Vol 3 (9) ◽  
pp. 1272-1277 ◽  
Author(s):  
Barry Chiswell ◽  
John F. Geldard ◽  
Arpad T. Phillip ◽  
Francis Lions
Keyword(s):  
Coordination Compounds ◽  
Chelate Compounds

The Preparation of p(acrylonitrile-co-acrylamide) hydrogels for uranyl ion recovery from aqueous environments

2014 ◽  
Vol 1 (42) ◽  
pp. 89-89 ◽  
Author(s):  
Duygu Alpaslan ◽  
Nahit Aktas ◽  
Selehattin Yilmaz ◽  
Nurettin Sahiner
Keyword(s):  
Uranyl Ion ◽  
Aqueous Environments

On the reliability of volume-based thermodynamics for inorganic-organic salts and coordination compounds with uncharged ligands

2017 ◽  
Author(s):  
Robson de Farias
Keyword(s):  
Coordination Compound ◽  
Coordination Compounds ◽  
Formation Enthalpy ◽  
Lattice Energy ◽  
Chemical Hardness ◽  
Acid Anion ◽  
Organic Salts ◽  
Density Values ◽  
Lattice Energies

In the present work, the reliability of the volume-based thermodynamics (VBT) methods in the calculation of lattice energies is investigated by applying the “traditional” Kapustinskii equation [8], as well as Glasser-Jenkins [3] and Kaya [5] equations to calculate the lattice energies for Na, K and Rb pyruvates [9-11] as well as for the coordination compound [Bi(C<sub>7</sub>H<sub>5</sub>O<sub>3</sub>)<sub>3</sub>C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>] [17] (in which C<sub>12</sub>H<sub>8</sub>N<sub>2</sub> = 1,10 phenathroline and C<sub>7</sub>H<sub>5</sub>O<sub>3</sub><sup>-</sup>= <i>o</i>-hyddroxybenzoic acid anion). As comparison, the lattice energies are also calculated using formation enthalpy values for sodium pyrivate and [Bi(C<sub>7</sub>H<sub>5</sub>O<sub>3</sub>)<sub>3</sub>C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>]. For the pyruvates, is verified that none of the considered approach, Kapustinskii, Glasser, Kaya or density, provides values that agrees in an acceptable % difference, with the lattice energy values calculated from the formation enthalpy values. However, it must be pointed out that Kaya approach, with deals with a chemical hardness approach is the better one for such kind of inorganic-organic salts. Based on data obtained for [Bi(C<sub>7</sub>H<sub>5</sub>O<sub>3</sub>)<sub>3</sub>C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>] is concluded that the only one VBT method that provides reliable lattice energies for compounds with bulky uncharged ligands is that one based on density values (derived by Glasser-Jenkins).

Molecular kinetic aspects of the vapo¬rization processes of volatile coordination compounds with organic ligands

2017 ◽  
Vol 58 (8) ◽  
pp. 1534-1542
Author(s):  
V.V. Lukashov ◽  
◽  
M.S. Makarov ◽  
S.N. Makarova ◽  
I.K. Igumenov ◽  
...  
Keyword(s):  
Coordination Compounds ◽  
Organic Ligands

ASSESSMENT OF TOXICITY OF GERMANIUM COORDINATION COMPOUNDS

2019 ◽  
pp. 16-21
Author(s):  
A. V. Kadomtsevа ◽  
I. V. Zhdanovich ◽  
M. S. Piskunovа ◽  
A. N. Lineva ◽  
A. N. Novikova ◽  
...  
Keyword(s):  
Coordination Compounds ◽  
Organometallic Compounds ◽  
Biologically Active ◽  
Pharmacological Properties ◽  
Toxicological Studies ◽  
Methods Of Synthesis ◽  
Promising Area

The synthesis of biologically active coordination compounds and the design on their basis of effective pharmacological preparations is currently the promising area. This paper presents the results of the toxicological studies on digermanium and its complex derivatives. It should be noted that the positive medical properties of organometallic compounds of germanium are confirmed by numerous studies, therefore, the development of the methods of synthesis, as well as investigations of physicochemical and pharmacological properties of these compounds are at the center of attention.

Sign in / Sign up

Export Citation Format

Share Document