Dielectric Properties of Alkyl Amides. II. Liquid Dielectric Constant and Loss

1964 ◽  
Vol 68 (3) ◽  
pp. 509-515 ◽  
Author(s):  
S. J. Bass ◽  
W. I. Nathan ◽  
R. M. Meighan ◽  
R. H. Cole
2008 ◽  
Vol 5 (1) ◽  
pp. 2-7 ◽  
Author(s):  
Khalid Z. Rajab ◽  
Mira Naftaly ◽  
Edmund H. Linfield ◽  
Juan C. Nino ◽  
Daniel Arenas ◽  
...  

Applications for low-temperature cofired ceramics (LTCC) and high-temperature cofired ceramics (HTCC) are advancing to higher frequencies. In order to design ceramic microsystems and electronic packages, the electrical properties of materials must be well characterized over a broad frequency range. In this study, the dielectric properties of commercial aluminum oxide (Al2O3) with different glass loadings are characterized using three different measurement techniques: the split-post cavity, terahertz (THz) time-domain spectroscopy, and Fourier transform IR spectroscopy (FTIR). Specifically, the dielectric properties will be characterized from 10 GHz to IR frequencies. A split-post cavity was employed for determination of dielectric properties in the 10 GHz range. A broadband THz spectroscopy technique was used to characterize the specimens using measured time-domain transmission data. The dielectric constant and loss were extracted from the sample's frequency-domain transmission characteristics, providing data between 100 GHz and 2 THz. Additionally, FTIR was used to characterize the samples from ~33 to 3300 cm−1 (~1–100 THz). The measurements from the three techniques are compared, and dielectric constant and loss data will be presented for commercial and experimental ceramic systems from 10 GHz to IR frequencies.


2019 ◽  
Vol 63 (1) ◽  
pp. 9-15
Author(s):  
Tibor Rovensky ◽  
Peter Lukacs ◽  
Alena Pietrikova

This paper is focused on investigation of dielectric properties of various substrates for InkJet printing technology. In addition this paper included investigation of dielectric properties' homogeneity. Dielectric constant and loss tangent of polymeric flexible substrates (Polyimide DuPont Kapton HN, PET Mylar A, PEN Teonex Q51) and insulation paper (Nomex 410) were measured in GHz frequency area. Measurements were done by combination of vector network analyzer and split cylinder resonator. This measuring method provides dielectric properties at frequency around 10 GHz, the exact value of frequency may vary depends on specific material and its resonant frequency. Experiments included two types of samples, 6 x 6 cm which is recommended area for measurements of dielectric properties by split cylinder resonator and 12 x 12 cm for measurements of dielectric properties' homogeneity (one sheet contains 9 overlapping measuring areas 6 x 6 cm). All measured values of dielectric constant and dielectric losses were statistically processed and depicted by SigmaPlot software. The paper shows values of dielectric properties at GHz frequency area as they are lacking in datasheets from manufacturers and evaluate homogeneity of measured substrates.


2012 ◽  
Vol 512-515 ◽  
pp. 1180-1183
Author(s):  
Qian Qian Jia ◽  
Hui Ming Ji ◽  
Shan Liu ◽  
Xiao Lei Li ◽  
Zheng Guo Jin

The (Ba, Sr)TiO3 (hereafter BST) ceramics are promising candidate for applying in tunable devices. MgO coated BST-Mg2TiO4 (BSTM-MT) composite ceramics were prepared to obtain the low dielectric constant, low dielectric loss, good dielectric constant temperature stability, and high tunability of BST ceramics. The Ba0.55Sr0.40Ca0.05TiO3 nanoparticles were coated with MgO using the precipitation method and then mixed with Mg2TiO4 powders to fabricate BSTM-MT composite ceramics. The morphologies, phases, elements, and dielectric properties of the sintered ceramics were investigated. The core-shell structure of BST powder wrapped with MgO was clearly observed from the TEM image. After sintered at 1100 °C for 2 h, the composite ceramics expressed dense microstructures from SEM images and two main phases BST and Mg2TiO4 were detected in the XRD patterns. The dielectric constant and loss tangent were both reduced after the coating. The reduced dielectric constant and loss tangent of BSTM-MT were 190, 0.0011 (2MHz), respectively. The ceramics exhibited the diffuse phase transition near the Curie temperature and the Curie temperature shifted from 10 °C to 5 °C after the coating. Since the continuous Ti-O bonds were disconnected with the MgO coating, the tunability was reduced to 15.14 % under a DC bias field of 1.1 kV/mm. The optimistic dielectric properties made it useful for the application of tunable capacitors and phase shifters.


2020 ◽  
Vol 19 (04) ◽  
pp. 1950034
Author(s):  
V. Balachandar ◽  
J. Brijitta ◽  
K. Viswanathan ◽  
R. Sampathkumar

In this study, ZnO–Fe2O3 nanocomposites were prepared by high-energy ball milling technique and characterized through X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), UV–visible spectroscopy and dielectric spectroscopy. The amount of Fe2O3 in the ZnO–Fe2O3 nanocomposites was varied at the rates of 1[Formula: see text]wt.%, 3[Formula: see text]wt.% and 5[Formula: see text]wt.% in order to investigate its influence on the structural, optical and dielectric properties of the nanocomposites. XRD patterns of nanocomposites revealed no shift in peak positions and hence confirmed the formation of composites after ball milling. Further, it was observed from FESEM analysis that Fe2O3 particles were distributed randomly on the ZnO matrix of the nanocomposites. ZnO–Fe2O3 nanocomposites reveal extended optical absorption in the range of 400–600[Formula: see text]nm from UV studies. The dielectric constant and loss of the nanocomposites decrease exponentially with increase in frequency. The composition and frequency dependences of the dielectric constant, dielectric loss and AC conductivity are explained based on the Maxwell–Wagner effect and Koop’s theory.


Polymers ◽  
2021 ◽  
Vol 13 (17) ◽  
pp. 2908
Author(s):  
Hailong Chen ◽  
Yudong Xu ◽  
Mengqi Liu ◽  
Tao Li

According to specific formulas, the mixing of rubber samples occurs by two methods: open mixing and internal mixing. The effects of frequency, mixing process, carbon black (CB) content, zinc oxide (ZnO) content, and stearic acid (SA) content on the dielectric properties of rubber materials were studied. The results showed that the effects of the mixing process on the dielectric properties of the rubber samples cannot be ignored, and the appropriate mixing process should be selected when preparing the required rubber materials. The dielectric constant and loss factor of the rubber samples vary depending on the frequency. The dielectric constant had a peak and valley value, while the loss factor only had a peak. The dielectric constant and loss factor of rubber samples were significantly affected by the content of CB, ZnO, and SA. The peak frequency decreased with the increase in CB content, however, the dielectric constant increased with an increase in CB content. The higher the ZnO content, the lower the peak frequency. In addition, the dielectric constant and loss factor increased with an increase in ZnO content. The higher the SA content, the greater the peak frequency. In addition, the dielectric constant and loss factor decreased with an increase in SA content. It is hoped that the experimental results obtained can provide guidance for the study of the dielectric properties, microwave absorption properties, and microwave heating characteristics of rubber polymers.


2017 ◽  
Vol 31 (32) ◽  
pp. 1750260 ◽  
Author(s):  
Aanchal Rawat ◽  
Trilok Chandra Upadhyay

In this paper, the ferroelectric transition and dielectric properties of the lead monohydrogen phosphate (PbHPO4) crystal are theoretically investigated. By using Green’s function method and modified two sublattice pseudospin–lattice coupled mode model, formulae for PbHPO4 type crystals are derived. Temperature variations of ferroelectric mode frequency, dielectric constant and loss tangent are calculated for the PbHPO4 crystal. Our results agree well with the experimental data.


2011 ◽  
Vol 1312 ◽  
Author(s):  
Xiaobing Shan ◽  
Lin Zhang ◽  
Z.-Y. Cheng

AbstractA high dielectric constant was observed in 0-3 composites using P(VDF-TrFE) copolymer as matrix and CaCu3TiO4 (CCTO) ceramic powders as fillers with a composition of 50 vol% CCTO. CCTO-P(VDF-TrFE) 0-3 composites with a CCTO content from 0 to 50 vol% were prepared and their dielectric properties, including frequency dependence and temperature dependence of the dielectric constant and loss, were characterized. It was experimentally observed that the hot-press process, inlcuding the configuration and hot-press time, has a strong influence on the dielectric properties of the composites. Additionally, the influence of the CCTO partice size on the dielectric properties of the composites was studied.


2012 ◽  
Vol 19 (06) ◽  
pp. 1250063 ◽  
Author(s):  
ZHAO DU ◽  
XUEHONG ZHANG ◽  
YUNLONG YUE ◽  
HAITAO WU

The effect of MgO on structure and dielectric properties of aluminoborosilicate glasses was investigated. FTIR data indicated that glass network was mainly built by tetrahedral [ SiO4 ], [ BO4 ], [ AlO4 ] and trigonal [ BO3 ]. A small amount of AlO5 or AlO6 units also existed. The glass system was characterized with lower dielectric constant (4.17 ~ 4.6) and dielectric loss (12.3 × 10-4 ~ 14.77 × 10-4) at 1 MHz. With the increase of MgO content, the quantity of AlO5 or AlO6 units decreased. The variation of density showed a decreasing tendency. The dielectric constant and loss were all found to decrease.


Geophysics ◽  
1973 ◽  
Vol 38 (1) ◽  
pp. 135-139 ◽  
Author(s):  
W. Hansen ◽  
W. R. Sill ◽  
S. H. Ward

Basaltic samples of known chemical composition were measured for dielectric constant and loss tangent in the frequency range 100 hz to 50 Mhz. All samples were prepared and measured by a contact substitution method in a dry nitrogen atmosphere at room temperature. The measurements indicated a general spectrum of dielectric constant with a range of 10–65 at 100 hz to 7–15 at 50 Mhz with frequency dispersion observed to be minimal above 1 Mhz. The loss tangent decreases from a range .2–.9 at 100 hz to a range .02–.15 at 100 khz. A finer‐grained sample was observed to have higher dielectric properties below 1 Mhz than a coarser‐grained sample of identical composition. A qualitative and subsequent quantitative study of possible compositional effects indicated that iron‐titanium compounds may be responsible for observed variations in the dielectric spectra of typical basalts.


2012 ◽  
Vol 535-537 ◽  
pp. 844-850
Author(s):  
Hui Na Ma ◽  
Zhi Min Yang ◽  
Jun Du

AlN-Mo composite ceramics were prepared by spark plasma sintering (SPS) with AlN and Mo, introduction of Mo particles into the AlN matrix was through direct current magnetron sputtering, sol-gel and blending technology methods. The effect of Mo particles on densification, electrical conduction and dielectric properties of AlN ceramic was studied by XRD, SEM, dielectric frequency spectrum. The results indicate that dielectric constant of AlN-0.26vol.%Mo composite ceramics obtained by sputtering increase by 22.5% at 1MHz as compared to the pure AlN sample; AlN-18vol.%Mo composite ceramics prepared with Mo powder coated with Al2O3 show insulator character and good dielectric properties; dielectric constant and loss of the composite ceramics increase with increasing the content of the elongated shape Mo particles, the highest dielectric constant and loss will be obtained when AlN-12vol.%Mo content is 30wt.% ( =98.41, tgδ=0.018 at 1MHz), the value of electrical resistivity decreases rapidly from 1.32×104 to 3.16×101Ω•cm when AlN-12vol.%Mo weight fraction increases from 30% to 40%.


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