Rates of mercapto proton exchange of mercaptoacetic acid in acetic acid

1970 ◽  
Vol 74 (1) ◽  
pp. 202-205 ◽  
Author(s):  
Jerry F. Whidby ◽  
Donald E. Leyden
Keyword(s):  
Acetic Acid ◽  
Proton Exchange ◽  
Mercaptoacetic Acid

Spectroscopic analysis of proton exchange during the photocatalytic decomposition of aqueous acetic acid: an isotopic study on the product distribution and reaction rate

2018 ◽  
Vol 8 (22) ◽  
pp. 5886-5899 ◽  
Author(s):  
Saher Hamid ◽  
Ralf Dillert ◽  
Jenny Schneider ◽  
Detlef W. Bahnemann
Keyword(s):  
Carbon Dioxide ◽  
Acetic Acid ◽  
Molecular Hydrogen ◽  
Reaction Rate ◽  
Spectroscopic Analysis ◽  
Product Distribution ◽  
Proton Exchange ◽  
Photocatalytic Decomposition ◽  
Aqueous Acetic Acid ◽  
Isotopic Study

The photocatalytic decomposition of aqueous acetic acid into molecular hydrogen, carbon dioxide, and hydrocarbons employing platinized titania (Pt/TiO2) as a photocatalyst has been studied.

Proton Exchange of Neopentyl Alcohol in Acetic Acid

1965 ◽  
Vol 87 (12) ◽  
pp. 2551-2554 ◽  
Author(s):  
Michael Cocivera ◽  
Ernest Grunwald
Keyword(s):  
Acetic Acid ◽  
Proton Exchange

scholarly journals INVESTIGATION OF THE DIRECTION OF THE REACTIONS OF MERCAPTOACETIC ACID ESTERS WITH EPI- AND THIOEPICHLOROHYDRINS

2020 ◽  
pp. 49-52
Author(s):  
K.Z. Guseinov ◽  
◽  
M.A. Mirzoeva ◽  
Keyword(s):  
Acetic Acid ◽  
Sodium Hydroxide ◽  
Alkaline Medium ◽  
Equimolar Amount ◽  
Mercaptoacetic Acid ◽  
Acetic Acid Esters ◽  
Acid Esters

The reactions of mercaptoacetic acid ethers with epi- and thio-epichlorohydrin in alkaline medium have been investigated. It was found that the reaction of mercaptoacetic acid esters with epichlorohydrin in the presence of an equimolar amount of sodium hydroxide simultaneously produces 2,3-epoxy¬pro-pylalkoxycarbonylmethyl sulfides and 1-chlor-3-alkoxycarbonylmethylthiol-2-propanols. Under using sodium hydroxide is used as a catalyst, only 1-chlorine-3-alkoxycarbonylmethyltio-2-propa-nols are obtained the reaction of mercaptoacetic acid esters with epichlorohydrin. As a result of the interaction of mercapto-acetic acid esters with thioepichlorohydrin in the presence of equimolar amounts of sodium hydroxide, 2,3-epitiopropylalkoxycarbonylmethyl sulfides are formed as the only products of the reaction

Thiyl Radicals. II. Reactions of meso-Substituted Anthracene Derivatives with Oxygen and Mercaptoacetic Acid

1963 ◽  
Vol 16 (5) ◽  
pp. 845 ◽  
Author(s):  
ALJ Beckwith ◽  
LB See
Keyword(s):  
Acetic Acid ◽  
Free Radical ◽  
Hydrogen Atom ◽  
Alkyl Substituent ◽  
Mercaptoacetic Acid ◽  
Hydrogen Atom Abstraction ◽  
Chain Mechanism ◽  
Radical Chain ◽  
Thiyl Radicals ◽  
Anthracene Derivatives

9-Methyl- and 9-benzylanthracene each react readily with mercaptoacetic acid and oxygen in benzene yielding (9-methyl-10-anthry1thio)acetic acid and(9-benzyl-10-anthry1thio)acetic acid respectively. There is no evidence for hydrogen atom abstraction from the alkyl substituent by free thiyl radicals. 9,10-Dimethylanthracene, when similarly treated, affords α-(carboxymethylthio)-9,10-dimethylanthracene, but 9,10-diphenylanthracene remains unaffected. These results are consistent with the free-radical-chain mechanism previously suggested.1

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