Electrical conductances and ionization behavior of sodium chloride in dioxane-water solutions at 100.deg. and pressures to 4000 bars

1971 ◽  
Vol 75 (8) ◽  
pp. 1099-1106 ◽  
Author(s):  
LeRoy B. Yeatts ◽  
Lawrence A. Dunn ◽  
William L. Marshall
1986 ◽  
Vol 41 (7) ◽  
pp. 939-943 ◽  
Author(s):  
E. Hawlicka

The self-diffusion coefficients of Na+, Cl- and I- in methanol-water solutions at 35 ± 0.01 °C have been measured in their dependence on the salt molarity in the range 1 · 10-4- 1 · 10-2 mol dm -3. The ionic self-diffusion coefficients in infinitely diluted solutions have been computed. The influence of the solvent composition on the solvation of the ions is discussed. A preferential hydration of Na+, Cl- and I- ions in water-methanol mixtures has been found.


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