Gas-phase addition reactions of trifluoromethyl and methyl radicals in hexafluoroazomethane-acetone mixtures. I

1971 ◽  
Vol 75 (6) ◽  
pp. 735-737 ◽  
Author(s):  
Charles E. Waring ◽  
Joseph D. Reardon
Keyword(s):  
Gas Phase ◽  
Addition Reactions ◽  
Methyl Radicals

ChemInform Abstract: Absolute Rate Measurements for Some Gas-Phase Addition Reactions of Dimethylsilylene

ChemInform ◽  
1988 ◽  
Vol 19 (39) ◽  
Author(s):  
J. E. BAGGOTT ◽  
M. A. BLITZ ◽  
H. M. FREY ◽  
P. D. LIGHTFOOT ◽  
R. WALSH
Keyword(s):  
Gas Phase ◽  
Addition Reactions ◽  
Absolute Rate

Detection of gas-phase methyl radicals using multiphoton ionization

1981 ◽  
Vol 82 (2) ◽  
pp. 267-269 ◽  
Author(s):  
T.G. Digiuseppe ◽  
Jeffrey W. Hudgens ◽  
M.C. Lin
Keyword(s):  
Gas Phase ◽  
Multiphoton Ionization ◽  
Methyl Radicals

THE REACTION OF METHYL RADICALS WITH FORMALDEHYDE

1959 ◽  
Vol 37 (9) ◽  
pp. 1462-1468 ◽  
Author(s):  
A. R. Blake ◽  
K. O. Kutschke
Keyword(s):  
Activation Energy ◽  
Kinetic Analysis ◽  
Addition Reactions ◽  
Methyl Radicals ◽  
Kcal Mole ◽  
A Value ◽  
Abstraction Reaction ◽  
Butyl Peroxide

The pyrolysis of di-t-butyl peroxide has been reinvestigated and used as a source of methyl radicals to study the abstraction reaction between methyl radicals and formaldehyde. At low [HCHO]/[peroxide] ratios the system was simple enough for kinetic analysis, and a value of 6.6 kcal/mole was obtained for the activation energy. At higher [HCHO]/[peroxide] ratios the system became very complicated, possibly due to the increased importance of addition reactions.

Formation of gas-phase methyl radicals over magnesium oxide

1985 ◽  
Vol 107 (1) ◽  
pp. 58-63 ◽  
Author(s):  
Daniel J. Driscoll ◽  
Wilson Martir ◽  
Ji Xiang Wang ◽  
Jack H. Lunsford
Keyword(s):  
Gas Phase ◽  
Magnesium Oxide ◽  
Methyl Radicals
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