Complex formation in aluminum iodide-diethyl ether solutions

1971 ◽  
Vol 75 (2) ◽  
pp. 282-284 ◽  
Author(s):  
Paul J. Ogren ◽  
James P. Cannon ◽  
Charles Frank Smith
Keyword(s):  
Complex Formation ◽  
Diethyl Ether ◽  
Aluminum Iodide

Liquid mixtures involving complex formation : Extensions of the ideal associated solution theory

1977 ◽  
Vol 30 (7) ◽  
pp. 1401 ◽  
Author(s):  
DV Fenby ◽  
A Chand ◽  
A Inglese ◽  
JE Grolier ◽  
HV Kehiaian
Keyword(s):  
Hydrogen Bond ◽  
Complex Formation ◽  
Diethyl Ether ◽  
Liquid Mixtures ◽  
Specific Interactions ◽  
Bond Properties ◽  
Solution Theory ◽  
Associated Solution ◽  
The Ideal

Extensions of the ideal associated solution theory which take into account intermolecular interaction and/or size factors are derived and applied to triethylamine+ CHCl3 and diethyl ether+CHCl3. Evidence is presented for non-hydrogen-bonding specific interactions between the unlike molecules in these systems. Theories that do not take this into consideration are likely to be unsatisfactory for the determination of hydrogen-bond properties. With respect to the evaluation of ?net complex formation? properties, the extensions considered do not represent significant improvements of the simple theory. The molar enthalpies of mixing of triethylamine+CH3CCl, and diethyl ether+ CH3CCl3 have been measured at 288.15 and 298.15 K.

Complex formation in liquid diethyl ether-chloroform mixtures examined by 2D correlation MID-IR spectroscopy

2016 ◽  
Vol 1124 ◽  
pp. 117-124 ◽  
Author(s):  
Andrii Kutsyk ◽  
Oleksii Ilchenko ◽  
Yuriy Pilgun ◽  
Vyacheslav Obukhovsky ◽  
Viktoria Nikonova
Keyword(s):  
Ir Spectroscopy ◽  
Complex Formation ◽  
Diethyl Ether

scholarly journals N-H···O hydrogen bonding: An FT-IR, NIR study of N-methylformamide-ether systems

2010 ◽  
Vol 75 (2) ◽  
pp. 157-163 ◽  
Author(s):  
Branislav Jovic ◽  
Aleksandar Nikolic ◽  
Erna Davidovic ◽  
Slobodan Petrovic
Keyword(s):  
Hydrogen Bonding ◽  
Carbon Tetrachloride ◽  
Complex Formation ◽  
Diethyl Ether ◽  
Equilibrium Constants ◽  
Electron Donors ◽  
Butyl Ether ◽  
Dibutyl Ether ◽  
Spectroscopic Characteristics ◽  
Ft Ir

This paper reports the results of an FT-IR and NIR study of N-methylformamide in carbon tetrachloride solution in presence of ethers as the O-electron donors, i.e., diethyl ether (DEE), diisopropyl ether (DiPE), methyl t- -butyl ether (MtBE), dibutyl ether (DBE), dipentyl ether (DPE), tetrahydrofuran (THF) and tetrahydropyran (THP). The spectroscopic characteristics of the N-H???O hydrogen bonded complexes are given. In addition, the equilibrium constants for 1:1 complex formation were determined at 25?C using Mid-IR and NIR measurements.

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