Partial molal volumes of gases dissolved in electrolyte solutions

1972 ◽  
Vol 76 (21) ◽  
pp. 3044-3049 ◽  
Author(s):  
E. W. Tiepel ◽  
K. E. Gubbins
Keyword(s):  
Electrolyte Solutions ◽  
Partial Molal Volumes ◽  
Molal Volumes

Solvent structure. III. The dependence of partial molal volumes on internal pressure and solvent compressibility

1976 ◽  
Vol 29 (4) ◽  
pp. 779 ◽  
Author(s):  
MRJ Dack
Keyword(s):  
Ascorbic Acid ◽  
Internal Pressure ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Solvent Structure ◽  
Pressure Data ◽  
Intrinsic Volumes ◽  
Volume Contraction ◽  
Partial Molal Volumes ◽  
Molal Volumes

Partial molal volumes, V�, at 25�C were measured for sucrose, ascorbic acid and aspirin in the solvents water, formamide, N,N-dimethylformamide and methanol. The dependence of V� on solvent compressibility enabled an estimate to be made of the intrinsic volumes, Vint, of the dissolved non-electrolytes. Effective pressures, Pe, in aqueous electrolyte solutions were calculated from previously determined internal pressure data. Substitution of Pe into the Tait-Gibson equation yielded values of Ve, the volume contraction of water due to electrostriction, which agree well with values obtained by other methods.

Partial Molal Volumes of Aqueous Ions

1957 ◽  
Vol 61 (10) ◽  
pp. 1426-1429 ◽  
Author(s):  
Loren G. Hepler
Keyword(s):  
Partial Molal Volumes ◽  
Aqueous Ions ◽  
Molal Volumes
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