Charge-transfer properties of the hydrogen bond. I. Theory of the enhancement of dipole moment of hydrogen-bonded systems

1972 ◽  
Vol 76 (21) ◽  
pp. 3000-3004 ◽  
Author(s):  
Henryk Ratajczak
RSC Advances ◽  
2015 ◽  
Vol 5 (46) ◽  
pp. 36279-36287 ◽  
Author(s):  
Jun-Sheng Chen ◽  
Feng-Jiao Zhao ◽  
Yang Yang ◽  
Tian-Shu Chu

Two different hydrogen bond effects on the photophysical properties of UPy systems in different solutions have been studied.


Evidence is presented that proton transfer occurs in certain special types of hydrogen bond and that as a direct result the association energy is increased. It is probable that this effect is also responsible for a t least a part of the broadening of the v XH absorption band. In support of this, a number of com pounds are described in which the hydrogen bonds are weakened by isotopic substitution. The implications of these findings are discussed.


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