Comparison of dynamic with isothermal techniques for the study of solid state decomposition kinetics

1972 ◽  
Vol 76 (10) ◽  
pp. 1474-1479 ◽  
Author(s):  
D. W. Johnson ◽  
P. K. Gallagher
Keyword(s):  
Solid State ◽  
Decomposition Kinetics ◽  
Solid State Decomposition

Thermal decomposition in the solid state

1975 ◽  
Vol 28 (6) ◽  
pp. 1169 ◽  
Author(s):  
W Ng
Keyword(s):  
Thermal Decomposition ◽  
Kinetic Equation ◽  
Solid State ◽  
Conventional Method ◽  
Differential Form ◽  
Kinetic Equations ◽  
Decomposition Kinetics ◽  
Solid State Decomposition ◽  
Decomposition Time ◽  
Decomposition Curve

The foundation of solid state decomposition kinetics is based on the well known theory of nucleation and nucleus growth put forward by Jacobs and Tompkins. It has now been shown that all the kinetic equations thus derived can be represented by a general differential form: ������������������������� dα/dt = kα1-p(1-α)1-q in which α, t and k are respectively the fractional decomposition, time and rate constant; while p and q are parameters lying between zero and unity inclusively. A method has been suggested to find p and q experimentally, thereby enabling one to find the appropriate kinetic form for the chemical decomposition. The conventional method involves the testing of various existing equations to the decomposition data. Different equations are found to fit over different ranges of the decomposition curve so that it is difficult to decide which is the correct kinetic equation for a particular reaction. The present approach however eliminates this complication.

Solid state decomposition studies on metal salicylates

1987 ◽  
Vol 114 (1) ◽  
pp. 145-152 ◽  
Author(s):  
Pertti Kokkonen ◽  
Lauri H.J. Lajunen ◽  
Leena Palmu
Keyword(s):  
Solid State ◽  
Solid State Decomposition

scholarly journals An Under-Appreciated Source of Reproducibility Issues in Cross-Coupling: Solid-State Decomposition of Primary Sodium Alkoxides in Air

ACS Catalysis ◽  
2020 ◽  
pp. 502-508
Author(s):  
Robert Wethman ◽  
Joseph Derosa ◽  
Van T. Tran ◽  
Taeho Kang ◽  
Omar Apolinar ◽  
...  
Keyword(s):  
Solid State ◽  
Cross Coupling ◽  
Solid State Decomposition

Electron Tomography Analysis of Reaction Path during Formation of Nanoporous NiO by Solid State Decomposition

2014 ◽  
Vol 14 (5) ◽  
pp. 2453-2459 ◽  
Author(s):  
A. K. Shukla ◽  
P. Ercius ◽  
A. R. S. Gautam ◽  
J. Cabana ◽  
U. Dahmen
Keyword(s):  
Solid State ◽  
Reaction Path ◽  
Electron Tomography ◽  
Solid State Decomposition ◽  
Tomography Analysis
Sign in / Sign up

Export Citation Format

Share Document