Ligand field theory of metal sandwich complexes. Axial field spin-orbit perturbation calculations for d1(d9), d2(d8), and d3(d7) configurations

1973 ◽  
Vol 77 (13) ◽  
pp. 1681-1686 ◽  
Author(s):  
Keith D. Warren
Keyword(s):  
Field Theory ◽  
Ligand Field ◽  
Spin Orbit ◽  
Sandwich Complexes ◽  
Axial Field ◽  
Ligand Field Theory ◽  
Orbit Perturbation

Über die Spin-Bahn-Wechselwirkung in der Ligandenfeldtheorie

1963 ◽  
Vol 18 (3) ◽  
pp. 276-280
Author(s):  
H.-H. Schmidtke
Keyword(s):  
Field Theory ◽  
Ligand Field ◽  
Spin Orbit Coupling ◽  
Spin Orbit ◽  
Field Potentials ◽  
Coupling Energy ◽  
Ligand Field Theory ◽  
Transition Series ◽  
Low Symmetry ◽  
Made In

The spin-orbit coupling operators in ligand field theory for octahedral, tetragonal, trigonal and axial symmetry are derived from the corresponding crystal field potentials. An estimate of the coupling energy for the low symmetry part of this operator is made in the case of octahedrally symmetric complexes of the first transition series. The results are discussed and compared with other approaches to this problem.

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