Pulse radiolytic study of the site of hydroxyl radical attack on aliphatic alcohols in aqueous solution

1973 ◽  
Vol 77 (10) ◽  
pp. 1218-1221 ◽  
Author(s):  
K. D. Asmus ◽  
H. Moeckel ◽  
A. Henglein
Keyword(s):  
Aqueous Solution ◽  
Hydroxyl Radical ◽  
Aliphatic Alcohols ◽  
Radical Attack

Heterogeneous Fenton Catalytic Removal of Organic Pollutant in Aqueous Solution by using Coal Gangue as a Catalyst

2019 ◽  
Vol 12 (4) ◽  
pp. 312-325
Author(s):  
Jiwei Zhang ◽  
Jingjing Xu ◽  
Shuaixia Liu ◽  
Baoxiang Gu ◽  
Feng Chen ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Peroxide ◽  
Hydroxyl Radical ◽  
Removal Rate ◽  
Organic Pollutant ◽  
Coal Gangue ◽  
Ion Leakage ◽  
Heterogeneous Fenton ◽  
Solution Ph ◽  
X Ray

Background: Coal gangue was used as a catalyst in heterogeneous Fenton process for the degradation of azo dye and phenol. The influencing factors, such as solution pH gangue concentration and hydrogen peroxide dosage were investigated, and the reaction mechanism between coal gangue and hydrogen peroxide was also discussed. Methods: Experimental results showed that coal gangue has the ability to activate hydrogen peroxide to degrade environmental pollutants in aqueous solution. Under optimal conditions, after 60 minutes of treatment, more than 90.57% of reactive red dye was removed, and the removal efficiency of Chemical Oxygen Demand (COD) up to 72.83%. Results: Both hydroxyl radical and superoxide radical anion participated in the degradation of organic pollutant but hydroxyl radical predominated. Stability tests for coal gangue were also carried out via the continuous degradation experiment and ion leakage analysis. After five times continuous degradation, dye removal rate decreased slightly and the leached Fe was still at very low level (2.24-3.02 mg L-1). The results of Scanning Electron Microscope (SEM), energy dispersive X-Ray Spectrometer (EDS) and X-Ray Powder Diffraction (XRD) indicated that coal gangue catalyst is stable after five times continuous reuse. Conclusion: The progress in this research suggested that coal gangue is a potential nature catalyst for the efficient degradation of organic pollutant in water and wastewater via the Fenton reaction.

Photopotential and photocurrent induced by an aqueous solution of aliphatic alcohols

1996 ◽  
Vol 96 (1-3) ◽  
pp. 161-165 ◽  
Author(s):  
Peter Markov ◽  
Malina Novkirishka ◽  
Khalid Aljanapy
Keyword(s):  
Aqueous Solution ◽  
Aliphatic Alcohols

Titanium Dioxide Nanoparticle Photocatalysed Degradation of Ibuprofen and Naproxen in Water: Competing Hydroxyl Radical Attack and Oxidative Decarboxylation by Semiconductor Holes

2018 ◽  
Vol 3 (39) ◽  
pp. 10915-10924 ◽  
Author(s):  
Andreia Romeiro ◽  
M. Emília Azenha ◽  
Moisés Canle ◽  
Victor H. N. Rodrigues ◽  
José P. Da Silva ◽  
...  
Keyword(s):  
Titanium Dioxide ◽  
Hydroxyl Radical ◽  
Oxidative Decarboxylation ◽  
Titanium Dioxide Nanoparticle ◽  
Radical Attack

Mechanism of O(3P) Formation from a Hydroxyl Radical Pair in Aqueous Solution

2015 ◽  
Vol 11 (10) ◽  
pp. 4740-4748 ◽  
Author(s):  
Edelsys Codorniu-Hernández ◽  
Kyle Wm. Hall ◽  
A. Daniel Boese ◽  
Daniel Ziemianowicz ◽  
Sheelagh Carpendale ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydroxyl Radical ◽  
Radical Pair

scholarly journals Comparison of hydrogen atom and hydroxyl radical reactions with simple aromatic molecules in aqueous solution

2020 ◽  
Vol 534 ◽  
pp. 110754 ◽  
Author(s):  
Renáta Homlok ◽  
Viktória Mile ◽  
Erzsébet Takács ◽  
Gábor Járvás ◽  
Szabolcs Góger ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Atom ◽  
Hydroxyl Radical ◽  
Radical Reactions ◽  
Aromatic Molecules
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