Binary diffusion coefficients for the system helium-chlorotrifluoromethane at 300.deg.K and 1 atmosphere. Test of the Chapman-Enskog theory

1973 ◽  
Vol 77 (5) ◽  
pp. 703-704 ◽  
Author(s):  
M. A. Yabsley ◽  
P. J. Carson ◽  
Peter J. Dunlop
Keyword(s):  
Diffusion Coefficients ◽  
Enskog Theory ◽  
Binary Diffusion ◽  
Binary Diffusion Coefficients

The Concentration Dependences of the Binary Diffusion Coefficients of the Systems H2–Ne, D2–Ne, H2–N2, D2–N2, H2–Ar, and D2–Ar at 1 Atm Pressure and 300 K

1972 ◽  
Vol 50 (14) ◽  
pp. 1644-1647 ◽  
Author(s):  
K. R. Harris ◽  
T. N. Bell ◽  
Peter J. Dunlop
Keyword(s):  
Mole Fraction ◽  
Diffusion Coefficients ◽  
Experimental Error ◽  
Similar Data ◽  
Enskog Theory ◽  
Intermolecular Potentials ◽  
Binary Diffusion ◽  
Concentration Dependences ◽  
Binary Diffusion Coefficients

Binary diffusion coefficients have been measured as a function of concentration for the systems H2–Ne, D2–Ne, D2–N2, H2–Ar, and D2–Ar at 1 atm pressure and 300 K. Similar data have already been presented for the system H2–N2. As predicted by the Chapman–Enskog theory, the concentration dependences of the diffusion coefficients for the systems containing deuterium are somewhat less than for the corresponding systems containing hydrogen. The data for the systems containing Ne and N2 indicate that there may be differences between the parameters required to describe the assumed spherical intermolecular potentials for the systems H2–Ne and D2–Ne, and also for the systems H2–N2 and D2–N2. The concentration dependences of the diffusion coefficients of all six systems are, within the estimated experimental error of ±0.2%, linear in the mole fraction of the heavier component in each system, x2.

The Concentration Dependence at 1 atm Pressure and 300 °K of the Binary Diffusion Coefficients of the Systems Helium – Carbon Dioxide, Helium – Nitrous Oxide, and Helium – Sulfur Hexafluoride

1972 ◽  
Vol 50 (12) ◽  
pp. 1874-1876 ◽  
Author(s):  
Kenneth R. Harris ◽  
T. N. Bell ◽  
Peter J. Dunlop
Keyword(s):  
Carbon Dioxide ◽  
Nitrous Oxide ◽  
Diffusion Coefficient ◽  
Concentration Dependence ◽  
Mole Fraction ◽  
Diffusion Coefficients ◽  
Sulfur Hexafluoride ◽  
Enskog Theory ◽  
Binary Diffusion ◽  
Binary Diffusion Coefficients

Binary diffusion coefficients are reported for the systems He–CO2, He–N2O, and He–SF6. In agreement with the Chapman–Enskog theory the concentration dependence of the diffusion coefficient of each system increases with the mole fraction of the heavier component.

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