Thermodynamics of ion solvation of the alkali metal chlorides in aluminum chloride-propylene carbonate solution

1974 ◽  
Vol 78 (25) ◽  
pp. 2576-2579
Author(s):  
Jacob Jorne ◽  
Charles W. Tobias
Keyword(s):  
Alkali Metal ◽  
Propylene Carbonate ◽  
Aluminum Chloride ◽  
Carbonate Solution ◽  
Ion Solvation ◽  
Alkali Metal Chlorides ◽  
Metal Chlorides

The effect of alkali metal chlorides and temperature on acid-hydrolysis residual pyrolysis products

2019 ◽  
Vol 137 ◽  
pp. 106-117 ◽  
Author(s):  
Qianqian Guo ◽  
Guanyi Chen ◽  
Zhanjun Cheng ◽  
Beibei Yan ◽  
Wenchao Ma ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Acid Hydrolysis ◽  
Alkali Metal Chlorides ◽  
Pyrolysis Products ◽  
Metal Chlorides

Reversible electrode potentials for formation of solid and liquid chlorozirconate and chlorohafnate compounds

1993 ◽  
Vol 71 (9) ◽  
pp. 1283-1289 ◽  
Author(s):  
G.J. Kipouros ◽  
S.N. Flengas
Keyword(s):  
Thermal Decomposition ◽  
Alkali Metal ◽  
Electrochemical Behaviour ◽  
Thermochemical Data ◽  
Dilute Solutions ◽  
Alkali Metal Chlorides ◽  
Metal Chlorides ◽  
Electrode Potentials ◽  
Standard Electrode Potentials

The standard electrode potentials for the formation of the pure solid and molten compounds Li2ZrCl6, Li2HfCl6, Na2ZrCl6, Na2HfCl6, K2ZrCl6, K2HfCl6, Cs2ZrCl6, and Cs2HfCl6 have been calculated from measured vapour pressures corresponding to their thermal decomposition at equilibrium and from available thermochemical data. Reversible potentials for the formation of Na2ZrCl6 and of K2ZrCl6 in solution according to the reaction[Formula: see text]where A is Na or K, have been calculated from available equilibrium vapour pressures as functions of the mole fractions of the alkali hexachlorocompounds. Standard potentials for the above reaction and "formal" potentials are also given. The latter are useful in predicting the electrochemical behaviour of dilute solutions of the hexachlorozirconates in alkali metal chlorides.

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