Charge-transfer complexes in organic chemistry. XI. Effect of acceptors on the properties of charge-transfer complexes formed by cyclic anhydrides

1974 ◽  
Vol 78 (10) ◽  
pp. 980-983 ◽  
Author(s):  
J. B. Nagy ◽  
O. B. Nagy ◽  
A. Bruylants
Keyword(s):  
Organic Chemistry ◽  
Charge Transfer ◽  
Charge Transfer Complexes ◽  
Cyclic Anhydrides

Charge-transfer complexes in organic chemistry—XII

Tetrahedron ◽  
1975 ◽  
Vol 31 (2) ◽  
pp. 135-141 ◽  
Author(s):  
S. Dupire ◽  
J.M. Mulindabyuma ◽  
J.B. Nagy ◽  
O.B. Nagy
Keyword(s):  
Organic Chemistry ◽  
Charge Transfer ◽  
Charge Transfer Complexes

scholarly journals Dialkyl dicyanofumarates and dicyanomaleates as versatile building blocks for synthetic organic chemistry and mechanistic studies

2017 ◽  
Vol 13 ◽  
pp. 2235-2251 ◽  
Author(s):  
Grzegorz Mlostoń ◽  
Heinz Heimgartner
Keyword(s):  
Organic Chemistry ◽  
Magnetic Properties ◽  
Charge Transfer ◽  
Reaction Mechanisms ◽  
Building Blocks ◽  
Charge Transfer Complexes ◽  
Mechanistic Studies ◽  
Oxidizing Agents ◽  
Michael Acceptors ◽  
Multistep Reactions

The scope of applications of dialkyl dicyanofumarates and maleates as highly functionalized electron-deficient dipolarophiles, dienophiles and Michael acceptors is summarized. The importance for the studies on reaction mechanisms of cycloadditions is demonstrated. Multistep reactions with 1,2-diamines and β-aminoalcohols leading to diverse five- and six-membered heterocycles are discussed. Applications of dialkyl dicyanofumarates as oxidizing agents in the syntheses of disulfides and diselenides are described. The reactions with metallocenes leading to charge-transfer complexes with magnetic properties are also presented.

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