Electrical conductance and ultrasonic relaxation for lithium perchlorate in tetrahydrofuran

1974 ◽  
Vol 78 (9) ◽  
pp. 917-925 ◽  
Author(s):  
Paul Jagodzinski ◽  
Sergio Petrucci
1980 ◽  
Vol 84 (4) ◽  
pp. 341-349 ◽  
Author(s):  
David Saar ◽  
Joseph Brauner ◽  
Herman Farber ◽  
Sergio Petrucci

1981 ◽  
Vol 42 (C6) ◽  
pp. C6-611-C6-613
Author(s):  
M. Boissier ◽  
R. Vacher ◽  
B. Perrin

1985 ◽  
Vol 46 (C10) ◽  
pp. C10-87-C10-90 ◽  
Author(s):  
K. R. MASCHHOFF ◽  
A. V. GRANATO

2000 ◽  
Vol 628 ◽  
Author(s):  
G. González ◽  
P. J. Retuert ◽  
S. Fuentes

ABSTRACTBlending the biopolymer chitosan (CHI) with poly (aminopropilsiloxane) oligomers (pAPS), and poly (ethylene oxide) (PEO) in the presence of lithium perchlorate lead to ion conducting products whose conductivity depends on the composition of the mixture. A ternary phase diagram for mixtures containing 0.2 M LiClO4 shows a zone in which the physical properties of the products - transparent, flexible, mechanically robust films - indicate a high degree of molecular compatibilization of the components. Comparison of these films with binary CHI-pAPS nanocomposites as well as the microscopic aspect, thermal behavior, and X-ray diffraction pattern of the product with the composition PEO/CHI/pAPS/LiClO4 1:0.5:0.6:0.2 molar ratio indicates that these films may be described as a layered nanocomposite. In this composite, lithium species coordinated by PEO and pAPS should be inserted into chitosan layers. Electrochemical impedance spectroscopy measurements indicate the films are pure ionic conductors with a maximal bulk conductivity of 1.7*10-5 Scm-1 at 40 °C and a sample-electrode interface capacitance of about 1.2*10-9 F.


Author(s):  
V. G. Kostrovskii ◽  
E. D. Litman ◽  
T. G. Shishmakova ◽  
I. L. Kotlyarevskii ◽  
M. I. Bardamova

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