Temperature dependence of limiting heat capacities of dissolution of tetrabutylphosphonium bromide, tetraphenylphosphonium bromide, and tetraphenylarsonium chloride in water and hydrophobic hydration

1974 ◽  
Vol 78 (7) ◽  
pp. 738-741 ◽  
Author(s):  
S. Sunder ◽  
B. Chawla ◽  
J. C. Ahluwalia
Keyword(s):  
Temperature Dependence ◽  
Hydrophobic Hydration ◽  
Heat Capacities ◽  
Tetraphenylphosphonium Bromide ◽  
Tetrabutylphosphonium Bromide ◽  
Tetraphenylarsonium Chloride

Temperature dependence of solvation heat capacities by gas chromatography

2005 ◽  
Vol 549 (1-2) ◽  
pp. 134-139 ◽  
Author(s):  
Zoltan A. Fekete ◽  
Károly Héberger ◽  
Zoltán Király ◽  
Miklós Görgényi
Keyword(s):  
Gas Chromatography ◽  
Temperature Dependence ◽  
Heat Capacities

scholarly journals Analysis of Two-State Folding Using Parabolic Approximation II: Temperature-Dependence

2016 ◽  
Author(s):  
Robert S Sade
Keyword(s):  
Protein Folding ◽  
Gibbs Energy ◽  
Temperature Dependence ◽  
Rate Constants ◽  
Heat Capacities ◽  
State System ◽  
Parabolic Approximation ◽  
Temperature Range ◽  
Gibbs Energies ◽  
Novel Treatment

Equations that govern the temperature-dependence of the rate constants, Gibbs energies, enthalpies, entropies and heat capacities of activation for folding and unfolding of spontaneously-folding fixed two-state systems have been derived using a procedure that treats the denatured and the native conformers as being confined to harmonic Gibbs energy wells. The notion that a two-state system is physically defined only for a set temperature range is introduced. The implications of this novel treatment for protein folding are discussed.

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