Partial volume expansibility of simple organic solutes from the temperature of maximum density of aqueous solutions

1975 ◽  
Vol 79 (20) ◽  
pp. 2105-2107 ◽  
Author(s):  
James R. Kuppers
1977 ◽  
Vol 55 (5) ◽  
pp. 798-799 ◽  
Author(s):  
James R. Kuppers

The shift in the temperature of maximum density for aqueous solutions customarily has been dissected into an ideal and a structural contribution. This analysis demonstrates that the dissection leads to the formulation of an ideal state which is attained by a fortuitous superposition of temperature dependent properties of pure components and, hence, cannot serve as a reliable reference state for comparing the influence of different solutes upon solution structure.


2019 ◽  
Vol 64 (12) ◽  
pp. 5847-5856 ◽  
Author(s):  
Jacobo Troncoso ◽  
Diego González-Salgado ◽  
Luis Romaní

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