Solute-solvent interactions of metal chelate and onium electrolytes by study of viscosity and apparent molal volume in methanol, acetone, and nitrobenzene

1975 ◽  
Vol 79 (16) ◽  
pp. 1664-1670 ◽  
Author(s):  
Toshihiro Tominaga
Keyword(s):  
Metal Chelate ◽  
Apparent Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions

scholarly journals INTERACTION STUDIES OF AMINO ACIDS IN AQUEOUS SODIUM BROMIDE SOLUTIONS AT DIFFERENT TEMPERATURE

2017 ◽  
Vol 5 (10) ◽  
pp. 160-167
Author(s):  
Yasmin Akhtar
Keyword(s):  
Amino Acids ◽  
Infinite Dilution ◽  
Adiabatic Compressibility ◽  
Sodium Bromide ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions ◽  
Aqueous Sodium ◽  
Bonding Effect

Densities, ultrasonic velocities and viscosities of L- Valine and L- Phenylalanine in aqueous sodium bromide (0.00, 0.025 and 0.05) m solutions have been determined experimentally at 308 and 313 K. The results obtained from density ultrasonic velocity and viscosity measurement have been used to calculate the apparent molal volume, фv, apparent molal, adiabatic compressibility ф Ks, partial molal volume ф0v at infinite dilution, partial molal adiabatic compressibility ф0Ks at infinite dilution, transfer volume ∆ф(tr), experimental slopes Sv and SKs,Falkenhagen coefficient A and  Jones-Dole B coefficient. The results are discussed in terms of the dehydration effect of the sodium bromide upon the amino acids and weak solute- solute and strong solute- solvent interactions. The properties of these amino acids in water and water + sodium bromide solution systems are discussed in terms of the charge, size and hydrogen bonding effect.

scholarly journals Study of Physical Properties for Sodium acetate with Water and Water - Acetone mixtures at Different Temperatures

2017 ◽  
Vol 27 (4) ◽  
Author(s):  
Ahmed Mohammed Abbas ◽  
Zainab Wajdi Ahmed ◽  
Alaa Fadhil Sulaiman ◽  
Issam AbdalKreem AbdalLatif
Keyword(s):  
Sodium Acetate ◽  
Apparent Molal Volume ◽  
Viscosity Data ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions ◽  
Acetone Water ◽  
Thermodynamic Activation Parameter ◽  
Different Temperatures ◽  
Apparent Molal Compressibility

In this study binary and ternary solutions are prepared by using the sodium acetate concentrations (0.1, 0.125, 0.2, 0.25, 0.4, 0.5, 0.8, 1 M) in water and acetone –water mixtures .The important parameters such as apparent molal volume, the partial molal volume transfer,  apparent  molal compressibility, free energy of activation of viscous flow and thermodynamic activation parameter (enthalpy and entropy) determined of sodium acetate in water , 20%, 40% ,60% and 80% V/V acetone –water mixtures at 298.15K, 303.15K, and 308.15K from density and viscosity measurements espectively. The limiting apparent molal volumes and experimental slopes were derived from the Masson equation, have been interpreted in terms of solute–solvent and solute–solute interactions  respectively. The viscosity data were analyzed using theJones–Dole equation and the derived parameter B - coefficient has also been interpreted in terms of solute–solvent interactions in the solutions. 

Ultrasonic and Density Studies of D(+) Mannose with Aqueous Electrolytes at 303K

2014 ◽  
Vol 1051 ◽  
pp. 215-220 ◽  
Author(s):  
Yasmin Akhtar
Keyword(s):  
Adiabatic Compressibility ◽  
Ternary Systems ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interaction ◽  
Solvent Interactions ◽  
Alkali Metal Halides ◽  
Experimental Values ◽  
Apparent Molal Adiabatic Compressibility

The present experimental investigation was carried out in order to explore the possible molecular interactions of D(+) mannose with mixed solvent of aqueous NaCl, KCl , MgCl2and CaCl2at 303 K. Experimental values of densities and ultrasonic velocities were carried out of the ternary mixture solution D(+) mannose with aqueous NaCl ,KCl, MgCl2and CaCl2. Aqueous alkali metal halides (NaCl ,KCl , MgCl2and CaCl2) were added under different molalities with D(+) mannose. The related and relevant parameters correlated to the present study such as adiabatic compressibility Ks, acoustic impedance Z, apparent molal volume фv, apparent molal adiabatic compressibility, фKs, and partial molal volume ф0vand partial molal adiabatic compressibility, фoKsat infinite dilution. The present investigation has exploited the possible molecular associations such as ion-ion, ion-solvent, solute-solute and solute-solvent interactions in these systems. It has been observed that there exist strong solute-solvent interaction and complex formation between in these ternary systems.

scholarly journals SOLUTE-SOLUTE AND SOLUTE-SOLVENT INTERACTIONS STUDIES OF SACCHARIDES IN AQUEOUS SODIUM BUTYRATE SOLUTION AT 308K TEMPERATURES

2020 ◽  
Vol 6 (11) ◽  
pp. 10-17
Author(s):  
Yasmin Akhtar ◽  
S. M. Yasin
Keyword(s):  
Aqueous Solution ◽  
Sodium Butyrate ◽  
Ternary Systems ◽  
Apparent Molal Volume ◽  
Partial Molal Volume ◽  
Molal Volume ◽  
Solvent Interactions ◽  
Bonding Effect ◽  
Solute Interactions ◽  
Hydrogen Bonding Effect

Density and viscosity of D (+) galactose and D (+) lactose mono hydrates in aqueous solution of sodium butyrate solutions have been determined experimentally at 308 K. The results obtained from density and viscosity measurement have been used to calculate the, apparent molal volume фv, partial molal volume ф0v, transfer volume ∆ф0tr at infinite dilution, A and B coefficient and Sv experimental slope. The results are interpreted in terms of solute-co- solute and solute-solvent interactions in these systems. It has been observed that there exist strong solute-solvent and solute-solute interactions and complex formation between in these ternary systems. The properties of the D (+) galactose and D (+) lactose mono hydrates in aqueous solution of sodium butyrate solutions are discussed in terms of the structure making and hydrogen bonding effect.

Thermodynamic properties of aqueous organic solutes in relation to their structure. Part III. Apparent molal volumes and heat capacities of low molecular weight alcohols and polyols at 25 °C

1976 ◽  
Vol 54 (4) ◽  
pp. 624-631 ◽  
Author(s):  
Carmel Jolicoeur ◽  
Ghyslain Lacroix
Keyword(s):  
Butyl Alcohol ◽  
Heat Capacities ◽  
Apparent Molal Volume ◽  
Molal Volume ◽  
Specific Effects ◽  
Alkyl Groups ◽  
Tert Butyl Alcohol ◽  
Dilute Aqueous Solutions ◽  
Solute Interactions ◽  
Molal Volumes

The density and specific heat of dilute aqueous solutions of various alcohols and polyols have been measured at 25 °C. Such measurements have been carried out for the following solutes: methanol, ethanol, n-propanol, n-butanol, isobutanol, s-butanol, tert-butyl alcohol, n-pentanol. 3-pentanol, neo-pentanol, ethyleneglycol, 1,4-butanediol, 1,6-hexanediol, dimethyl-2,2-propanediol, 1,1,1-tris(hydroxymethyl)ethane, and pentaerythritol.The limiting apparent molal volume [Formula: see text] and heat capacities [Formula: see text] derived from these data exhibit some variations among the properties of isomers (e.g. branched vs. normal alkyl groups), but these variations cannot be conclusively attributed to specific effects in the hydration of the alkyl groups. On the other hand, the data allows one to derive group contributions to [Formula: see text] and [Formula: see text] namely [Formula: see text] for the methylene group, [Formula: see text] for the OH functional group and [Formula: see text] for the C—H of a terminal methyl group.The concentration dependence of [Formula: see text] brings out some interesting new features. With most of the alcohols, [Formula: see text] decreases with concentration, in a way related to the degree of hydrophobicity of the alcohol. Solute–solute interactions contribute to reduce [Formula: see text] of the hydrophilic solutes, but the opposite effect is observed with the most hydrophobic alcohols.

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