Monomer mobility and solid state polymerization of alkali metal acrylates

1976 ◽  
Vol 80 (10) ◽  
pp. 1057-1059 ◽  
Author(s):  
Pier P. Saviotti ◽  
D. F. R. Gilson
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Solid State Polymerization

Driving Force for the Thermally Induced Solid State Polymerization of Alkali Metal Halogenoacetates:  A Thermochemical Analysis

2002 ◽  
Vol 106 (41) ◽  
pp. 10764-10770 ◽  
Author(s):  
Ana L. C. Lagoa ◽  
Hermínio P. Diogo ◽  
Manuel E. Minas da Piedade ◽  
Karsten Schwarz ◽  
Matthias Epple
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Driving Force ◽  
Thermally Induced ◽  
Solid State Polymerization

Influence of Alkali Metal Cations on the Photodimerization of Bromo Cinnamates Studied by Solid-State NMR

2020 ◽  
Vol 124 (50) ◽  
pp. 27614-27620
Author(s):  
Marufa Zahan ◽  
He Sun ◽  
Sophia E. Hayes ◽  
Harald Krautscheid ◽  
Jürgen Haase ◽  
...  
Keyword(s):  
Solid State ◽  
Alkali Metal ◽  
Solid State Nmr ◽  
Metal Cations ◽  
Alkali Metal Cations

Synthesis of New Chalcogenide Materials. The Novel One-Dimensional Semiconductor K4 Ti3 S14

1987 ◽  
Vol 97 ◽  
Author(s):  
Steven A. Sunshine ◽  
Doris Kang ◽  
James A. Ibers
Keyword(s):  
Electrical Conductivity ◽  
Solid State ◽  
Alkali Metal ◽  
The Novel ◽  
Conductivity Measurements ◽  
One Dimensional ◽  
General Utility ◽  
Solid State Materials ◽  
Chalcogenide Materials

ABSTRACTThe use of A2 Q/Q melts (A - alkali metal, Q - S or Se) for the synthesis of new one-dimensional solid-state materials is found to be of general utility and is illustrated here for the synthesis of K4 Ti3 SI4. Reaction of Ti metal with a K2 S/S melt at 375°C for 50 h affords K4 Ti3 SI4. The structure possesses one-dimensional chains of seven and eightcoordinate Ti atoms with each chain isolated from all others by surrounding K atoms. There are six S-S pairs (dave - 2.069(3) Å) so that the compound is one of TiIV and may be described as K4 [Ti3 (S)2 (S2)6]. Electrical conductivity measurements indicate that this material is a semiconductor.

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