Reduction of mercuric halides and pseudohalides in aqueous solution. Formation and some physicochemical properties of mercury(I) chloride, mercury(I) bromide, mercury(I) iodide, mercury(I) thiocyanate, and mercury(I) cyanide radical molecules

1976 ◽  
Vol 80 (10) ◽  
pp. 1049-1053 ◽  
Author(s):  
H. Jungbluth ◽  
J. Beyrich ◽  
K. D. Asmus
Author(s):  
A. Legrouri

The industrial importance of metal catalysts supported on reducible oxides has stimulated considerable interest during the last few years. This presentation reports on the study of the physicochemical properties of metallic rhodium supported on vanadium pentoxide (Rh/V2O5). Electron optical methods, in conjunction with other techniques, were used to characterise the catalyst before its use in the hydrogenolysis of butane; a reaction for which Rh metal is known to be among the most active catalysts.V2O5 powder was prepared by thermal decomposition of high purity ammonium metavanadate in air at 400 °C for 2 hours. Previous studies of the microstructure of this compound, by HREM, SEM and gas adsorption, showed it to be non— porous with a very low surface area of 6m2/g3. The metal loading of the catalyst used was lwt%Rh on V2Q5. It was prepared by wet impregnating the support with an aqueous solution of RhCI3.3H2O.


2012 ◽  
Vol 9 (1) ◽  
pp. 22-25
Author(s):  
S.V. Amel’kin ◽  
D.Ye. Igoshin

A self-assembly model for porous hydrate structures is proposed, which takes into account the sequence of basic physical processes: hydrate growth on the surface of the aqueous solution, formation of islet structure, capillary flow, separation and transfer of secondary crystallization nuclei to the meniscus. The model was studied within the cellular automata method. A good correspondence between the results of the simulation and the experimental data is obtained.


1989 ◽  
Vol 62 (4) ◽  
pp. 1032-1036 ◽  
Author(s):  
Kenji Ikeda ◽  
Motoharu Ishikawa ◽  
Masaaki Yasuda ◽  
Kunio Esumi ◽  
Kenjiro Meguro ◽  
...  

2004 ◽  
Vol 43 (11) ◽  
pp. 3341-3343 ◽  
Author(s):  
John D. Gilbertson ◽  
Nathaniel K. Szymczak ◽  
David R. Tyler

2011 ◽  
Vol 23 (5) ◽  
pp. 1158-1165 ◽  
Author(s):  
Jian-Li Mi ◽  
Thomas N. Jensen ◽  
Mogens Christensen ◽  
Christoffer Tyrsted ◽  
Jens E. Jørgensen ◽  
...  

2008 ◽  
Vol 26 (4) ◽  
pp. 413-422
Author(s):  
Z. Xu ◽  
Y. Tian ◽  
M. Zhu ◽  
W. Qiao ◽  
Z. Li ◽  
...  

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