Positive ion-molecule reactions in the methyl chloride- and ethyl chloride-ammonia systems

1978 ◽  
Vol 82 (15) ◽  
pp. 1679-1682 ◽  
Author(s):  
Zygmunt Luczynski ◽  
Jan A. Herman
Keyword(s):  
Methyl Chloride ◽  
Ethyl Chloride ◽  
Ion Molecule Reactions ◽  
Positive Ion

An ICR mass spectrometry study of ion/molecule reactions between ethyl chloride and alkylamines

1991 ◽  
Vol 69 (2) ◽  
pp. 363-367
Author(s):  
Guoying Xu ◽  
Jan A. Herman
Keyword(s):  
Mass Spectrometry ◽  
Key Words ◽  
Rate Constant ◽  
Rate Constants ◽  
Ethyl Chloride ◽  
Ion Molecule Reactions ◽  
Mass Spectrometry Study ◽  
Ethyl Cation

Ion/molecule reactions in mixtures of ethyl chloride with C1–C4 alkylamines were studied by ICR mass spectrometry. Ethyl cation transfer to C1–C4 alkylamines proceeds mainly through diethylchloronium ions with rate constants ~3 × 10−10cm3 s−1. In the case of s-butylamine the corresponding rate constant is 0.5 × 10−10 cm3 s−1. Key words: ICR mass spectrometry, ion/molecule reactions, ethylchloride, methylamine, ethylamine, propylamines, butylamines

Negative Ion Mass Spectra of Organic Nitriles

1981 ◽  
Vol 35 (1) ◽  
pp. 85-88 ◽  
Author(s):  
Kenneth L. Bush ◽  
Carol E. Parker ◽  
Donald J. Harvan ◽  
Maurice M. Bursey ◽  
J. Ronald Hass
Keyword(s):  
Mass Spectra ◽  
Chemical Ionization ◽  
Detection Limits ◽  
Negative Ion ◽  
Ionization Source ◽  
Ion Molecule Reactions ◽  
Residual Oxygen ◽  
Chemical Ionization Source ◽  
Positive Ion

Negative ion mass spectra organic nitriles have been determined using 1 Torr of methane moderator/reagent gas in a chemical ionization source. The spectra contain abundant (M – 1)− ions, and fragmentations are minimal. Ion/molecule reactions with residual oxygen, methane, and between sample molecules and ions form diverse products with low abundances relative to the ( M – 1)−. Detection limits are comparable with positive ion methods, and for selected compounds, can be several orders of magnitude lower.

scholarly journals Ion?Molecule Reactions and Mobilities of SF3+ and SF5+ Ions in SF6 Gas

1993 ◽  
Vol 46 (6) ◽  
pp. 799 ◽  
Author(s):  
ZA Talib ◽  
M Saporoschenko
Keyword(s):  
Field Strength ◽  
Electric Field ◽  
Electric Field Strength ◽  
Drift Tube ◽  
Ion Source ◽  
Zero Field ◽  
Number Density ◽  
Mobility Data ◽  
Ion Molecule Reactions ◽  
Positive Ion

Positive ion-molecule reactions in 8F6 were studied in a static drift-tube mass spectrometer using electron impact at 100 eY as the ion source. The ratio of electric field strength to gas number density, E / N, was typically varied from 40-282 Td and pressure ranged from 0�1 to o� 8 Torr. The most important processes were found to be 8Ft + SF6 ---+ 8Ft + 8F6 + F2 and 8Ft + 8F6 ---+ (82Fg)+* ---+ 82Ft + F 2. The interaction potentials for the 8Ft and 8Ft ions in SF6 were also found by using the measured mobility data which were obtained using a pulsed-ion transit-time method. We found that the (12,4, a* = 0�1) core model was adequate to describe the mobility over the range of E / N studied. The zero-field reduced mobilities for 8Ft and 8Ft were determined to be 0�68 and 0�55cm2y-1 s- 1 respectively.

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