Kinetics and mechanism of the oxidation of ferrous ion by iodate ion in strong perchloric acid, aqueous media

1979 ◽  
Vol 83 (18) ◽  
pp. 2328-2335 ◽  
Author(s):  
James G. Brummer ◽  
Richard J. Field
Keyword(s):  
Perchloric Acid ◽  
Aqueous Media ◽  
Kinetics And Mechanism ◽  
Ferrous Ion

scholarly journals THE RATE CONSTANT OF THE REACTION BETWEEN FERROUS IONS AND HYDROGEN PEROXIDE IN ACID SOLUTION

1957 ◽  
Vol 35 (5) ◽  
pp. 428-436 ◽  
Author(s):  
T. J. Hardwick
Keyword(s):  
Hydrogen Peroxide ◽  
Acid Solution ◽  
Sulphuric Acid ◽  
Acid Concentration ◽  
Rate Constant ◽  
Perchloric Acid ◽  
Ferrous Ion ◽  
Ferrous Ions ◽  
Bimolecular Rate Constant

Identical values of the bimolecular rate constant of the ferrous ion – hydrogen peroxide reaction were obtained from intercomparisons of the methods previously used in following this reaction. In perchloric acid the bimolecular rate constant is unaffected by acid concentration; in sulphuric acid it increases slightly in acid concentrations above 10−2N. The results agree with and explain the differences between those obtained by Baxendale and by Dainton, but are only in marginal agreement with those recently reported by Weiss.

Sign in / Sign up

Export Citation Format

Share Document