Flash photolysis-resonance fluorescence kinetic study of the reactions hydroxyl + molecular hydrogen .fwdarw. water + atomic hydrogen and hydroxyl + methane .fwdarw. water + methyl from 298 to 1020 K

1980 ◽  
Vol 84 (23) ◽  
pp. 3126-3130 ◽  
Author(s):  
F. P. Tully ◽  
A. R. Ravishankara

This paper describes the measurement of charge transfer cross-sections for protons, molecular hydrogen ions and helium ions in the rare gases and hydrogen, and electron detachment cross-sections for negative atomic hydrogen ions in the rare gases. Part I describes the energy range 3 to 40 keV. In part II the energy range 100 to 4000 eV is described, and the results are discussed in terms of the pseudo-adiabatic hypothesis. Comparisons are made with other experimental results, and anomalous molecular cases are discussed in terms of reactions involving anti-bonding states.


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