High-pressure study of the viscosity effects on the intramolecular excimer formation in 1,3-di(1-pyrenyl)propane

1986 ◽  
Vol 90 (18) ◽  
pp. 4265-4268 ◽  
Author(s):  
Kimihiko Hara ◽  
Hiroyuki Yano
Keyword(s):  
High Pressure ◽  
Viscosity Effects ◽  
Intramolecular Excimer ◽  
Excimer Formation ◽  
High Pressure Study

High Pressure Studies of Quantum Well Emission and Deep Emission in GaInP(ordered)-GaAs Heterostructures

1997 ◽  
Vol 499 ◽  
Author(s):  
S. H. Kwok ◽  
P. Y. Yu ◽  
K. Uchida ◽  
T. Arai
Keyword(s):  
High Pressure ◽  
Quantum Well ◽  
Emission Band ◽  
Excitation Power ◽  
High Excitation ◽  
High Pressure Studies ◽  
Band Alignments ◽  
High Pressure Study

ABSTRACTWe report on a high pressure study of emission from a series of GaInP(ordered)/GaAs heterostructures. A so-called “deep emission” band at 1.46 eV is observed in all our samples. At high excitation power, quantum well emission emerges in only one structure where thin GaP layers are inserted on both sides of the GaAs well. From the pressure dependent emission in this sample we have determined its band alignments. The role of the GaP layers in suppressing the deep emission is elucidated.

High-Pressure Study of Metallocenes, M(η5-C5H5)2(M = Fe, Co)

2007 ◽  
Vol 76 (Suppl.A) ◽  
pp. 31-32
Author(s):  
Sergey V. Ovsyannikov ◽  
Vladimir V. Shchennikov ◽  
Alexander N. Titov ◽  
Yoshiya Uwatoko
Keyword(s):  
High Pressure ◽  
High Pressure Study

In-situ high-pressure study of the ordered phase of ethyl propionate

2007 ◽  
Vol 63 (1) ◽  
pp. 111-117 ◽  
Author(s):  
Roman Gajda ◽  
Andrzej Katrusiak
Keyword(s):  
High Pressure ◽  
Degrees Of Freedom ◽  
Molecular Volume ◽  
Ethyl Propionate ◽  
Intermolecular Contacts ◽  
High Pressure Study ◽  
Pressure Phase ◽  
Three Degrees Of Freedom ◽  
Volume Difference

Ethyl propionate, C5H10O2 (m.p. 199 K), has been in-situ pressure-frozen and its structure determined at 1.34, 1.98 and 2.45 GPa. The crystal structure of the new high-pressure phase (denoted β) is different from phase α obtained by lowering the temperature. The freezing pressure of ethyl propionate at 296 K is 1.03 GPa. The molecule assumes an extended chain s-trans–trans–trans conformation, only slightly distorted from planarity. The closest intermolecular contacts in both phases are formed between carbonyl O and methyl H atoms; however, the ethyl-group H atoms in phase β form no contacts shorter than 2.58 Å. A considerable molecular volume difference of 24.2 Å3 between phases α and β can be rationalized in terms of degrees of freedom of molecules arranged into closely packed structures: the three degrees of freedom allowed for rearrangements of molecules confined to planar sheets in phase α, but are not sufficient for obtaining a densely packed pattern.

Sign in / Sign up

Export Citation Format

Share Document