Bimolecular reaction of a local mode vibrational state: hydrogen atom + water (4.nu.OH) .fwdarw. hydroxyl(v,J) + hydrogen

1990 ◽  
Vol 94 (11) ◽  
pp. 4391-4393 ◽  
Author(s):  
Amitabha. Sinha
Keyword(s):  
Hydrogen Atom ◽  
Vibrational State ◽  
Bimolecular Reaction ◽  
Local Mode

H-F−Potential Interaction and Local Mode Frequencies for an Interstitial Hydrogen Atom in Alkaline Earth Fluorides

1970 ◽  
Vol 2 (4) ◽  
pp. 1140-1148 ◽  
Author(s):  
W. M. Hartmann ◽  
T. L. Gilbert ◽  
K. A. Kaiser ◽  
A. C. Wahl
Keyword(s):  
Hydrogen Atom ◽  
Alkaline Earth ◽  
Potential Interaction ◽  
Local Mode ◽  
Interstitial Hydrogen

The missing NH stretch fundamental in S1 methyl anthranilate: IR-UV double resonance experiments and local mode theory

2020 ◽  
Vol 22 (25) ◽  
pp. 14077-14087
Author(s):  
Karl N. Blodgett ◽  
Joshua L. Fischer ◽  
Timothy S. Zwier ◽  
Edwin L. Sibert
Keyword(s):  
Infrared Spectroscopy ◽  
Hydrogen Atom ◽  
Double Resonance ◽  
Local Mode ◽  
Methyl Anthranilate ◽  
Mode Theory

Hydrogen atom dislocation in S1 methyl anthranilate is characterized with infrared spectroscopy, and a novel explanation for the missing S1 NH stretch fundamental is presented.

Oxidation of organic sulphides. I. Interaction of cyclo hexyl methyl sulphide with hydroperoxides in alcohols

1954 ◽  
Vol 224 (1158) ◽  
pp. 389-398 ◽  
Keyword(s):  
Hydrogen Atom ◽  
Oxygen Atom ◽  
Exchange Process ◽  
Reaction Rates ◽  
Bimolecular Reaction ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
First Order ◽  
Solvent Acidity

Cyclo hexyl methyl sulphide is oxidized quantitatively to the sulphoxide by alcoholic solutions of cyclo hexenyl and t -butyl hydroperoxides at moderate temperatures. Kinetically the oxida­tion appears to be a simple bimolecular reaction, first-order with respect to both the sulphide and hydroperoxide. However, the reaction rates vary in different alcohols in the order of varying solvent acidity, and correspondingly the addition of much stronger acids produces powerful catalysis. The solvent and the acids clearly play a part in the reaction, and it is concluded that the actual oxidant is a cyclic complex between the hydroperoxide and a hydrogen-donating molecule, oxygen atom transfer to the sulphide being promoted by a synchronous hydrogen atom exchange process within the complex. Energies and entropies of activation for the oxidation under various conditions are reported and their significance discussed.

The (5000) Local Mode Vibrational State of Germane: A High-Resolution Spectroscopic Study

1997 ◽  
Vol 184 (1) ◽  
pp. 12-21 ◽  
Author(s):  
Fu-ge Sun ◽  
Xiao-gang Wang ◽  
Jie-lou Liao ◽  
Qing-shi Zhu
Keyword(s):  
High Resolution ◽  
Spectroscopic Study ◽  
Vibrational State ◽  
Local Mode

Calculated versus measured vibrational state specific reactivity of hydrogen atom + fluorine

1993 ◽  
Vol 97 (33) ◽  
pp. 8578-8582 ◽  
Author(s):  
Xavier Gimenez ◽  
Josep M. Lucas ◽  
Antonio Aguilar ◽  
Antonio Lagana
Keyword(s):  
Hydrogen Atom ◽  
Vibrational State ◽  
Specific Reactivity
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