Solubility of cobalt(II) chloride in molten sodium chloride-aluminum chloride

1990 ◽  
Vol 94 (4) ◽  
pp. 1666-1669 ◽  
Author(s):  
Chien. Wai ◽  
Ira. Bloom ◽  
Deanna. Caveny ◽  
Milton. Blander
1994 ◽  
Vol 48 (3) ◽  
pp. 406-409
Author(s):  
E. M. Hondrogiannis ◽  
J. C. Coffield ◽  
D. S. Trimble ◽  
A. E. Edwards ◽  
G. Mamantov

The Raman, UV-visible, electron spin resonance spectroscopic, and spectroelectrochemical (SEC) behavior of tetrachloro- p-benzoquinone (chloranil) in molten aluminum chloride/sodium chloride mixtures has been examined. The results support previous findings suggesting that the chloranil is complexed by AlCl3or A12C17– in acidic melts [>50 mole percent (m/o) A1C13], while in basic melts (< 50 m/o A1C13) the chloranil remains uncomplexed. The results further support the previously proposed stepwise one-electron reductions in the acidic melt to produce the radical anion and the dianion. The present work, however, reveals that chloranil is also reduced through two closely spaced one-electron reductions in the basic melt.


2015 ◽  
Vol 1119 ◽  
pp. 334-337
Author(s):  
Xu Ling Wei ◽  
Yu Li Wei ◽  
Guang Bi Gong ◽  
Tao Liang ◽  
Wen Jing Cai ◽  
...  

Powdered polychloroprene rubber (PCR-244) was prepared by the direct condensation, and the influence of agglomerator kinds and dosages on powdering of PCR-244 were investigated, including trivalent salt (aluminum chloride), divalent salt (magnesium sulfate, calcium chloride) and monovalent salt (sodium chloride, potassium chloride). The result showed that powder chloroprene rubber could be used as adhesive material that calcium chloride was used as agglomerator.


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