Chronoamperometry of polypyrrole: migration of counterions and effect of uncompensated solution resistance

1988 ◽  
Vol 92 (24) ◽  
pp. 7002-7006 ◽  
Author(s):  
Chris D. Paulse ◽  
Peter G. Pickup
Keyword(s):  
2014 ◽  
Vol 609-610 ◽  
pp. 118-123
Author(s):  
Xiao Xing Yan ◽  
Guo Yue Xu ◽  
Yan Wu ◽  
Zhi Hui Wu

Cork flooring maintains the natural qualities of cork, showing the unique and elegant natural patterns, and also has series of advantages such as thermal insulation, sound insulation, moisture barrier, insulation, and no static. Ultraviolet (UV) curable coatings have no volatile organic compounds, little environmental pollution, fast curing, and are suitable for high speed automated production, which is the development of environmentally friendly wood floor coatings. In this paper, the UV-curable wooden coatings for floor were interfacially modified with nanosilica. The process parameters were optimized by orthogonal experiments, and the overall performance of wood flooring UV coating was obtained. The mechanical properties of the coating (hardness, adhesion and impact strength), resistance to liquid properties (resistance to aqueous sodium chloride solution, resistance to aqueous sodium hydroxide solution, resistance to alcohol, resistance to blue and black ink, resistance to sauce) and gloss were tested. It was found that wood flooring UV coating had good performance, hardness reached 3H, adhesion reached one grade, impact strength was 40 kgcm, and fluid-resistant performance (120 h) of coating reached one grade when the nanosilica content was 0.50%~0.70%, the drying time was 2 min, and medium pressure mercury UV lamp was 3. The gloss results showed that gloss of wood flooring UV coatings decreased with the increase of nanosilica content. When the nanosilica content was 0.50%~0.70%, the gloss value was in the vicinity of 35%, showing a matte gloss. This study provides new perspectives in wood flooring UV coating for industrial applications.


2017 ◽  
Vol 896 ◽  
pp. 97-103 ◽  
Author(s):  
Wen Hai Chen ◽  
Cheng You Wu ◽  
Hui Fang Zhang ◽  
Wu Yu Zhang ◽  
Bo Kun Chen ◽  
...  

Alternating current impedance has been used to study effects of hydration stages and molar ratio on the pore structure and hydration characters of basic magnesium sulfate cement. The alternating current impedance spectra of at early hydration almost appears as a straight line because none crystal hydration phases form. And it appears high frequency semicircle at late hydration stage because of decreasing of porosity and amount of 5Mg (OH)2 ·MgSO4·7H2O gradually form with ages. Besides, alternating current impedance spectra differences among basic magnesium sulfate, magnesium oxysulfate and magnesium oxychloride cement have been studied. These differences indicate that additives such as citric acid may change the structure and charge characteristics of MgO hydration layer which make tends to form more 5Mg (OH)2 ·MgSO4·7H2O phase in basic magnesium sulfate cement than that in magnesium oxysulfate cement. The higher pore solution resistance of BMS cement is the main factor of better steel-protection.


2011 ◽  
Vol 115 (24) ◽  
pp. 12232-12242 ◽  
Author(s):  
Shruti Srivastav ◽  
Rama Kant

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